Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis

<p> Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups...

Descripción completa

Detalles Bibliográficos
Autores: Romero, Martín, Fra,Laura, Lishchynskyi, Anton, Martínez, Claudio, Streuff, Jan, Muñiz, Kilian
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305859
Acceso en línea:http://hdl.handle.net/2072/305859
https://doi.org/10.1016/j.tet.2015.03.028
Access Level:acceso abierto
Palabra clave:Amination
Catalysis
C-H functionalization
Iodine
Oxidation
id ES_64ea467352e52a8a7d52504cd8627c71
oai_identifier_str oai:recercat.cat:2072/305859
network_acronym_str ES
network_name_str España
repository_id_str
spelling Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysisRomero, MartínFra,LauraLishchynskyi, AntonMartínez, ClaudioStreuff, JanMuñiz, KilianAminationCatalysisC-H functionalizationIodineOxidation<p> Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups onto activated alkenes. The resulting compounds can also be employed as catalyst precursors for transferhydrogenation.</p>Elsevier2015info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/2072/305859https://doi.org/10.1016/j.tet.2015.03.028RECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésMinisterio de Economia y CompetitivadExplora grants to K. M., and Severo Ochoa Excellence Accreditation 2014-2018 to ICIQ,Photoyodocat (Mineco Explora)TetrahedronCTQ2013-50105-EXP I I SEV-2013-03192016 Elsevier B.V.info:eu-repo/semantics/openAccessoai:recercat.cat:2072/3058592026-05-29T05:05:01Z
dc.title.none.fl_str_mv Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
title Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
spellingShingle Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
Romero, Martín
Amination
Catalysis
C-H functionalization
Iodine
Oxidation
title_short Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
title_full Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
title_fullStr Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
title_full_unstemmed Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
title_sort Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
dc.creator.none.fl_str_mv Romero, Martín
Fra,Laura
Lishchynskyi, Anton
Martínez, Claudio
Streuff, Jan
Muñiz, Kilian
author Romero, Martín
author_facet Romero, Martín
Fra,Laura
Lishchynskyi, Anton
Martínez, Claudio
Streuff, Jan
Muñiz, Kilian
author_role author
author2 Fra,Laura
Lishchynskyi, Anton
Martínez, Claudio
Streuff, Jan
Muñiz, Kilian
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Amination
Catalysis
C-H functionalization
Iodine
Oxidation
topic Amination
Catalysis
C-H functionalization
Iodine
Oxidation
description <p> Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups onto activated alkenes. The resulting compounds can also be employed as catalyst precursors for transferhydrogenation.</p>
publishDate 2015
dc.date.none.fl_str_mv 2015
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/305859
https://doi.org/10.1016/j.tet.2015.03.028
url http://hdl.handle.net/2072/305859
https://doi.org/10.1016/j.tet.2015.03.028
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Ministerio de Economia y Competitivad
Explora grants to K. M., and Severo Ochoa Excellence Accreditation 2014-2018 to ICIQ,
Photoyodocat (Mineco Explora)
Tetrahedron
CTQ2013-50105-EXP I I SEV-2013-0319
dc.rights.none.fl_str_mv 2016 Elsevier B.V.
info:eu-repo/semantics/openAccess
rights_invalid_str_mv 2016 Elsevier B.V.
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869409703209992192
score 15,811543

Similares en LA Referencia