Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis
<p> Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups...
| Autores: | , , , , , |
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| Tipo de documento: | artigo |
| Data de publicação: | 2015 |
| País: | España |
| Recursos: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositório: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305859 |
| Acesso em linha: | http://hdl.handle.net/2072/305859 https://doi.org/10.1016/j.tet.2015.03.028 |
| Access Level: | Acceso aberto |
| Palavra-chave: | Amination Catalysis C-H functionalization Iodine Oxidation |
| Resumo: | <p> Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups onto activated alkenes. The resulting compounds can also be employed as catalyst precursors for transferhydrogenation.</p> |
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