Amidato complexes of ruthenium, rhodium and iridium from concise NeH bond activation: exploration in catalysis

<p> Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups...

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Detalles Bibliográficos
Autores: Romero, Martín, Fra,Laura, Lishchynskyi, Anton, Martínez, Claudio, Streuff, Jan, Muñiz, Kilian
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305859
Acceso en línea:http://hdl.handle.net/2072/305859
https://doi.org/10.1016/j.tet.2015.03.028
Access Level:acceso abierto
Palabra clave:Amination
Catalysis
C-H functionalization
Iodine
Oxidation
Descripción
Sumario:<p> Acceptor-substituted N-H groups as found in carbamides and sulfonamides are readily activated through suitable unsaturated metal complexes applying the concept of metal-ligand bifunctionality. This process constitutes the basis for an enantioselective intramolecular addition of N-H groups onto activated alkenes. The resulting compounds can also be employed as catalyst precursors for transferhydrogenation.</p>