Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2

<p> &nbsp;</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> A user-friendly Ni-catalyzed reductive</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> cyclization/carb...

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Detalles Bibliográficos
Autores: Wang, Xueqiang, Liu, Yu, Martin, Ruben
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305841
Acceso en línea:http://hdl.handle.net/2072/305841
https://doi.org/10.1021/jacs.5b03340
Access Level:acceso abierto
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spelling Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2Wang, XueqiangLiu, YuMartin, Ruben<p> &nbsp;</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> A user-friendly Ni-catalyzed reductive</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> cyclization/carboxylation of <i>unactivated </i>alkyl halides</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> with CO<span style="font: 7.0px 'Times New Roman'">2 </span>is described. The protocol operates under mild</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> conditions with excellent chemoselectivity profile and a</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> divergent <i>syn/anti-</i>selectivity pattern that can be easily</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> modulated by the substrate utilized.</p>Journal of the American Chemical Society,2015info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/2072/305841https://doi.org/10.1021/jacs.5b03340RECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésiCIQ foundationthe European Research CouncilMINECOSevero Ochoa Excellence AccreditationEuropean UnionERC, MINECO , COFUND,CELLEXJ. Am. Chem. Socinfo:eu-repo/grantAgreement/ERC/FP7/277883MINECO (CTQ2012-34054)(SEV-2013-0319)© 2015 American Chemical Societyinfo:eu-repo/semantics/openAccessoai:recercat.cat:2072/3058412026-05-29T05:05:01Z
dc.title.none.fl_str_mv Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
title Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
spellingShingle Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
Wang, Xueqiang
title_short Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
title_full Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
title_fullStr Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
title_full_unstemmed Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
title_sort Ni-catalyzed Divergent Cyclization/Carboxylation of Unactivated Primary and Secondary Alkyl Halides with CO2
dc.creator.none.fl_str_mv Wang, Xueqiang
Liu, Yu
Martin, Ruben
author Wang, Xueqiang
author_facet Wang, Xueqiang
Liu, Yu
Martin, Ruben
author_role author
author2 Liu, Yu
Martin, Ruben
author2_role author
author
description <p> &nbsp;</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> A user-friendly Ni-catalyzed reductive</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> cyclization/carboxylation of <i>unactivated </i>alkyl halides</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> with CO<span style="font: 7.0px 'Times New Roman'">2 </span>is described. The protocol operates under mild</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> conditions with excellent chemoselectivity profile and a</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> divergent <i>syn/anti-</i>selectivity pattern that can be easily</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> modulated by the substrate utilized.</p>
publishDate 2015
dc.date.none.fl_str_mv 2015
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/305841
https://doi.org/10.1021/jacs.5b03340
url http://hdl.handle.net/2072/305841
https://doi.org/10.1021/jacs.5b03340
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv iCIQ foundation
the European Research Council
MINECO
Severo Ochoa Excellence Accreditation
European Union
ERC, MINECO , COFUND,CELLEX
J. Am. Chem. Soc
info:eu-repo/grantAgreement/ERC/FP7/277883
MINECO (CTQ2012-34054)
(SEV-2013-0319)
dc.rights.none.fl_str_mv © 2015 American Chemical Society
info:eu-repo/semantics/openAccess
rights_invalid_str_mv © 2015 American Chemical Society
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Journal of the American Chemical Society,
publisher.none.fl_str_mv Journal of the American Chemical Society,
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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