Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2

<p> A catalytic carboxylation of unactivated primary, secondary &amp; tertiary alkyl chlorides with CO<sub>2</sub> at atmospheric pressure is described. This protocol represents the first <em>intermolecular </em>cross-electrophile coupling of unactivated alkyl chlor...

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Detalles Bibliográficos
Autores: Börjesson, Marino, Moragas, Antoni, Martin, Ruben
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305936
Acceso en línea:http://hdl.handle.net/2072/305936
https://doi.org/10.1021/jacs.6b04088
Access Level:acceso abierto
Descripción
Sumario:<p> A catalytic carboxylation of unactivated primary, secondary &amp; tertiary alkyl chlorides with CO<sub>2</sub> at atmospheric pressure is described. This protocol represents the first <em>intermolecular </em>cross-electrophile coupling of unactivated alkyl chlorides, thus leading to new knowledge in the cross-coupling arena.</p>