Visible Light-Promoted Atom Transfer Radical Cyclization of Unactivated Alkyl Iodides

A visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the percep...

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Detalles Bibliográficos
Autores: Shen, Yangyang, Cornella, Josep, Juliá-Hernández, Francisco, Martin, Martin, Ruben
Tipo de recurso: artículo
Estado:Versión borrador
Fecha de publicación:2016
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/326409
Acceso en línea:http://hdl.handle.net/2072/326409
https://doi.org/10.1021%2Facscatal.6b03205%20
Access Level:acceso abierto
Palabra clave:Quimica
Descripción
Sumario:A visible-light-mediated atom transfer radical cyclization of unactivated alkyl iodides is described. This protocol operates under mild conditions and exhibits high chemoselectivity profile while avoiding parasitic hydrogen atom transfer pathways. Preliminary mechanistic studies challenge the perception that a canonical photoredox catalytic cycle is being operative.