Ni-catalyzed Carboxylation of Unactivated Primary Alkyl Bromides and Sulfonates with CO2
<p> </p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> A Ni-catalyzed carboxylation of <i>unactivated</i></p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'&qu...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2014 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305831 |
| Acceso en línea: | http://hdl.handle.net/2072/305831 https://doi.org/10.1021/ja5064586 |
| Access Level: | acceso abierto |
| Sumario: | <p> </p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> A Ni-catalyzed carboxylation of <i>unactivated</i></p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> primary alkyl bromides and sulfonates with CO<span style="font: 7.0px 'Times New Roman'">2 </span>at</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> atmospheric pressure is described. The method is characterized</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> by its mild conditions and a remarkable wide</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> scope without the need for air- or moisture-sensitive</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> reagents, thus becoming a user-friendly and operationally</p> <p style="margin: 0.0px 0.0px 0.0px 0.0px; font: 10.5px 'Times New Roman'"> simple protocol en route to carboxylic acids.</p> |
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