Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene

The synthesis of a set of new N-heteroaryltetramines is reported. A regioselective alkylation on the N-exo nitrogen of pyridinium N-(heteroaryl)aminide with the corresponding tetrabromo compounds, followed by a clean N–N bond reduction of the corresponding tetra-salts, allowed an easy and general me...

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Detalhes bibliográficos
Autores: Castillo Romero, Rafael|||0000-0003-1957-3098, Izquierdo Ceinos, María Luisa, Álvarez-Builla Gómez, Julio
Tipo de documento: artigo
Data de publicação:2007
País:España
Recursos:Universidad de Alcalá (UAH)
Repositório:e_Buah Biblioteca Digital Universidad de Alcalá
Idioma:inglês
OAI Identifier:oai:ebuah.uah.es:10017/2689
Acesso em linha:http://hdl.handle.net/10017/2689
https://dx.doi.org/10.1016/j.tetlet.2007.06.044
Access Level:Acceso aberto
Palavra-chave:Regioselective synthesis
Molecular recognition
Polyamine analogs
Ligands
Complexes
2-Aminopyridines
Derivatives
Receptors
Chemistry
N-(2'-azinyl)aminides
Chemistry, Organic
Bioquímica
Ciencia
Biochemistry
Science
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network_acronym_str ES
network_name_str España
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spelling Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzeneCastillo Romero, Rafael|||0000-0003-1957-3098Izquierdo Ceinos, María LuisaÁlvarez-Builla Gómez, JulioRegioselective synthesisMolecular recognitionPolyamine analogsLigandsComplexes2-AminopyridinesDerivativesReceptorsChemistryN-(2'-azinyl)aminidesChemistry, OrganicBioquímicaCienciaBiochemistryScienceThe synthesis of a set of new N-heteroaryltetramines is reported. A regioselective alkylation on the N-exo nitrogen of pyridinium N-(heteroaryl)aminide with the corresponding tetrabromo compounds, followed by a clean N–N bond reduction of the corresponding tetra-salts, allowed an easy and general method to obtain N,N′,N″,N‴-tetrakis(2-heteroaryl)tetramines.Ministerio de Educación y CienciaComisión Interministerial de Ciencia y TecnologíaElsevier20072007-01-01journal articlehttp://purl.org/coar/resource_type/c_6501NAhttp://purl.org/coar/version/c_be7fb7dd8ff6fe43info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10017/2689https://dx.doi.org/10.1016/j.tetlet.2007.06.044reponame:e_Buah Biblioteca Digital Universidad de Alcaláinstname:Universidad de Alcalá (UAH)InglésengCICYT Not available CTQ2005-08902 N-AMIDAS DE AZINIO ESTABILIZADAS POR HETEROARILO: REACCIONES A TRAVÉS DE ORGANOPALADIOS, SÍNTESIS DE POLIAMINAS DENDRÍMERAS Y REACCIONES RADICALARIASopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ebuah.uah.es:10017/26892026-06-18T11:13:07Z
dc.title.none.fl_str_mv Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene
title Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene
spellingShingle Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene
Castillo Romero, Rafael|||0000-0003-1957-3098
Regioselective synthesis
Molecular recognition
Polyamine analogs
Ligands
Complexes
2-Aminopyridines
Derivatives
Receptors
Chemistry
N-(2'-azinyl)aminides
Chemistry, Organic
Bioquímica
Ciencia
Biochemistry
Science
title_short Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene
title_full Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene
title_fullStr Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene
title_full_unstemmed Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene
title_sort Pyridinium N-heteroarylaminides: synthesis of N-heteroaryltetramines based on 1,6-bis(phenoxy)hexane and 1,3-bis(phenoxymethyl)benzene
dc.creator.none.fl_str_mv Castillo Romero, Rafael|||0000-0003-1957-3098
Izquierdo Ceinos, María Luisa
Álvarez-Builla Gómez, Julio
author Castillo Romero, Rafael|||0000-0003-1957-3098
author_facet Castillo Romero, Rafael|||0000-0003-1957-3098
Izquierdo Ceinos, María Luisa
Álvarez-Builla Gómez, Julio
author_role author
author2 Izquierdo Ceinos, María Luisa
Álvarez-Builla Gómez, Julio
author2_role author
author
dc.subject.none.fl_str_mv Regioselective synthesis
Molecular recognition
Polyamine analogs
Ligands
Complexes
2-Aminopyridines
Derivatives
Receptors
Chemistry
N-(2'-azinyl)aminides
Chemistry, Organic
Bioquímica
Ciencia
Biochemistry
Science
topic Regioselective synthesis
Molecular recognition
Polyamine analogs
Ligands
Complexes
2-Aminopyridines
Derivatives
Receptors
Chemistry
N-(2'-azinyl)aminides
Chemistry, Organic
Bioquímica
Ciencia
Biochemistry
Science
description The synthesis of a set of new N-heteroaryltetramines is reported. A regioselective alkylation on the N-exo nitrogen of pyridinium N-(heteroaryl)aminide with the corresponding tetrabromo compounds, followed by a clean N–N bond reduction of the corresponding tetra-salts, allowed an easy and general method to obtain N,N′,N″,N‴-tetrakis(2-heteroaryl)tetramines.
publishDate 2007
dc.date.none.fl_str_mv 2007
2007-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
NA
http://purl.org/coar/version/c_be7fb7dd8ff6fe43
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10017/2689
https://dx.doi.org/10.1016/j.tetlet.2007.06.044
url http://hdl.handle.net/10017/2689
https://dx.doi.org/10.1016/j.tetlet.2007.06.044
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv CICYT Not available CTQ2005-08902 N-AMIDAS DE AZINIO ESTABILIZADAS POR HETEROARILO: REACCIONES A TRAVÉS DE ORGANOPALADIOS, SÍNTESIS DE POLIAMINAS DENDRÍMERAS Y REACCIONES RADICALARIAS
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:e_Buah Biblioteca Digital Universidad de Alcalá
instname:Universidad de Alcalá (UAH)
instname_str Universidad de Alcalá (UAH)
reponame_str e_Buah Biblioteca Digital Universidad de Alcalá
collection e_Buah Biblioteca Digital Universidad de Alcalá
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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