(R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol

The molecules of the title compound, C27H28O2, exhibit axial chirality. The planes of the aromatic rings of the tetralin ring systems make an angle of 85.72 (11)°. The non-aromatic rings adopt distorted half-chair conformations. In one of them, two C atoms of the four-atom aliphatic chain are disord...

ver descrição completa

Detalhes bibliográficos
Autores: Abreu Sá, Artur, Ramos Silva, Manuela, Pereira, Mariette M., Bayón, Joan Carles|||0000-0002-2498-1945, Matos Beja, Ana
Tipo de documento: artigo
Data de publicação:2010
País:España
Recursos:Universitat Autònoma de Barcelona
Repositório:Dipòsit Digital de Documents de la UAB
Idioma:inglês
OAI Identifier:oai:ddd.uab.cat:108140
Acesso em linha:https://ddd.uab.cat/record/108140
https://dx.doi.org/urn:doi:10.1107/S1600536810002308
Access Level:Acceso aberto
Palavra-chave:Cristal·lografia
Crystallography
id ES_fa1173d12a6cf9d01964b67413c6bfeb
oai_identifier_str oai:ddd.uab.cat:108140
network_acronym_str ES
network_name_str España
repository_id_str
spelling (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-olAbreu Sá, ArturRamos Silva, ManuelaPereira, Mariette M.Bayón, Joan Carles|||0000-0002-2498-1945Matos Beja, AnaCristal·lografiaCrystallographyThe molecules of the title compound, C27H28O2, exhibit axial chirality. The planes of the aromatic rings of the tetralin ring systems make an angle of 85.72 (11)°. The non-aromatic rings adopt distorted half-chair conformations. In one of them, two C atoms of the four-atom aliphatic chain are disordered over two sites in a 0.75 (2):0.25 (2) ratio. The substituent phenyl ring is also disordered over two positions in a 0.59 (3):0.41 (3) ratio. There are no conventional hydrogen bonds joining the molecules 22010-01-0120102010-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/108140https://dx.doi.org/urn:doi:10.1107/S1600536810002308reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengopen accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:1081402026-06-06T12:50:31Z
dc.title.none.fl_str_mv (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
title (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
spellingShingle (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
Abreu Sá, Artur
Cristal·lografia
Crystallography
title_short (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
title_full (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
title_fullStr (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
title_full_unstemmed (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
title_sort (R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
dc.creator.none.fl_str_mv Abreu Sá, Artur
Ramos Silva, Manuela
Pereira, Mariette M.
Bayón, Joan Carles|||0000-0002-2498-1945
Matos Beja, Ana
author Abreu Sá, Artur
author_facet Abreu Sá, Artur
Ramos Silva, Manuela
Pereira, Mariette M.
Bayón, Joan Carles|||0000-0002-2498-1945
Matos Beja, Ana
author_role author
author2 Ramos Silva, Manuela
Pereira, Mariette M.
Bayón, Joan Carles|||0000-0002-2498-1945
Matos Beja, Ana
author2_role author
author
author
author
dc.subject.none.fl_str_mv Cristal·lografia
Crystallography
topic Cristal·lografia
Crystallography
description The molecules of the title compound, C27H28O2, exhibit axial chirality. The planes of the aromatic rings of the tetralin ring systems make an angle of 85.72 (11)°. The non-aromatic rings adopt distorted half-chair conformations. In one of them, two C atoms of the four-atom aliphatic chain are disordered over two sites in a 0.75 (2):0.25 (2) ratio. The substituent phenyl ring is also disordered over two positions in a 0.59 (3):0.41 (3) ratio. There are no conventional hydrogen bonds joining the molecules
publishDate 2010
dc.date.none.fl_str_mv 2
2010-01-01
2010
2010-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/108140
https://dx.doi.org/urn:doi:10.1107/S1600536810002308
url https://ddd.uab.cat/record/108140
https://dx.doi.org/urn:doi:10.1107/S1600536810002308
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869425151315017728
score 15,301603