(R)-2'-Benzyloxy-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl-2-ol
The molecules of the title compound, C27H28O2, exhibit axial chirality. The planes of the aromatic rings of the tetralin ring systems make an angle of 85.72 (11)°. The non-aromatic rings adopt distorted half-chair conformations. In one of them, two C atoms of the four-atom aliphatic chain are disord...
| Autores: | , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2010 |
| País: | España |
| Institución: | Universitat Autònoma de Barcelona |
| Repositorio: | Dipòsit Digital de Documents de la UAB |
| Idioma: | inglés |
| OAI Identifier: | oai:ddd.uab.cat:108140 |
| Acceso en línea: | https://ddd.uab.cat/record/108140 https://dx.doi.org/urn:doi:10.1107/S1600536810002308 |
| Access Level: | acceso abierto |
| Palabra clave: | Cristal·lografia Crystallography |
| Sumario: | The molecules of the title compound, C27H28O2, exhibit axial chirality. The planes of the aromatic rings of the tetralin ring systems make an angle of 85.72 (11)°. The non-aromatic rings adopt distorted half-chair conformations. In one of them, two C atoms of the four-atom aliphatic chain are disordered over two sites in a 0.75 (2):0.25 (2) ratio. The substituent phenyl ring is also disordered over two positions in a 0.59 (3):0.41 (3) ratio. There are no conventional hydrogen bonds joining the molecules |
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