Aqua(glycinato)(3,4,7,8-tetramethyl-1,10-phenanthroline)copper(II) Nitrate
In the title compound, [Cu(C2H4NO2)(C16H16N2)-(H2O)]NO3, CuII displays distorted square-pyramidal coordination where the water molecule is in the apical position and the base is defined by the N and one of the O atoms from the glycinate ligand, and both phenanthroline N atoms. The phenanthroline che...
| Autores: | , , , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1995 |
| País: | España |
| Institución: | Universitat Autònoma de Barcelona |
| Repositorio: | Dipòsit Digital de Documents de la UAB |
| Idioma: | inglés |
| OAI Identifier: | oai:ddd.uab.cat:27739 |
| Acceso en línea: | https://ddd.uab.cat/record/27739 https://dx.doi.org/urn:doi:10.1107/S0108270194013041 |
| Access Level: | acceso abierto |
| Palabra clave: | Cristal·lografia Crystallography |
| Sumario: | In the title compound, [Cu(C2H4NO2)(C16H16N2)-(H2O)]NO3, CuII displays distorted square-pyramidal coordination where the water molecule is in the apical position and the base is defined by the N and one of the O atoms from the glycinate ligand, and both phenanthroline N atoms. The phenanthroline chelate-ring plane (N1, C12, C11, N2, Cu) is slightly distorted from planarity, whereas the five-membered ring formed by the glycinate ligand (defined by atoms N3, C18, C17, O1 and Cu), presents a distorted half-chair conformation. |
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