Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]

The title compound [2(1,2,3,3a,6a-ƞ)pentalene]-[l(ƞ5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas...

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Detalles Bibliográficos
Autores: Álvarez-Fernández, Alejandra|||0000-0002-1906-0180, Briansó, José Luis, Piniella, J. Francesc|||0000-0002-0552-6285, Farran José, Joan|||0000-0002-5933-1176, Manríquez, Juan M., Chávez, Ivonne, Oelckers, Beatriz, Molins Grau, Elies|||0000-0003-1012-0551, Miravitlles Torras, Carles
Tipo de recurso: artículo
Fecha de publicación:1996
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:27737
Acceso en línea:https://ddd.uab.cat/record/27737
https://dx.doi.org/urn:doi:10.1107/S0108270196008037
Access Level:acceso abierto
Palabra clave:Cristal·lografia
Crystallography
Descripción
Sumario:The title compound [2(1,2,3,3a,6a-ƞ)pentalene]-[l(ƞ5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe-C distances, i.e. a mean value of 2.121(3)A for the Fe-Cbridge distances and a mean value of 2.028(3)A for the distances from the Fe atoms to all other Catoms. In the terminal pentalene ligand, the C-C and C-Fe distances in the ring bonded to the Fe atom are all similar.

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