Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]

The title compound [2(1,2,3,3a,6a-ƞ)pentalene]-[l(ƞ5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas...

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Autores: Álvarez-Fernández, Alejandra|||0000-0002-1906-0180, Briansó, José Luis, Piniella, J. Francesc|||0000-0002-0552-6285, Farran José, Joan|||0000-0002-5933-1176, Manríquez, Juan M., Chávez, Ivonne, Oelckers, Beatriz, Molins Grau, Elies|||0000-0003-1012-0551, Miravitlles Torras, Carles
Tipo de recurso: artículo
Fecha de publicación:1996
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:27737
Acceso en línea:https://ddd.uab.cat/record/27737
https://dx.doi.org/urn:doi:10.1107/S0108270196008037
Access Level:acceso abierto
Palabra clave:Cristal·lografia
Crystallography
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spelling Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]Álvarez-Fernández, Alejandra|||0000-0002-1906-0180Briansó, José LuisPiniella, J. Francesc|||0000-0002-0552-6285Farran José, Joan|||0000-0002-5933-1176Manríquez, Juan M.Chávez, IvonneOelckers, BeatrizMolins Grau, Elies|||0000-0003-1012-0551Miravitlles Torras, CarlesCristal·lografiaCrystallographyThe title compound [2(1,2,3,3a,6a-ƞ)pentalene]-[l(ƞ5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe-C distances, i.e. a mean value of 2.121(3)A for the Fe-Cbridge distances and a mean value of 2.028(3)A for the distances from the Fe atoms to all other Catoms. In the terminal pentalene ligand, the C-C and C-Fe distances in the ring bonded to the Fe atom are all similar. 11996-01-0119961996-01-01Articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://ddd.uab.cat/record/27737https://dx.doi.org/urn:doi:10.1107/S0108270196008037reponame:Dipòsit Digital de Documents de la UABinstname:Universitat Autònoma de BarcelonaInglésengopen accesshttp://purl.org/coar/access_right/c_abf2Aquest material està protegit per drets d'autor i/o drets afins. Podeu utilitzar aquest material en funció del que permet la legislació de drets d'autor i drets afins d'aplicació al vostre cas. Per a d'altres usos heu d'obtenir permís del(s) titular(s) de drets.https://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:ddd.uab.cat:277372026-06-06T12:50:31Z
dc.title.none.fl_str_mv Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
title Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
spellingShingle Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
Álvarez-Fernández, Alejandra|||0000-0002-1906-0180
Cristal·lografia
Crystallography
title_short Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
title_full Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
title_fullStr Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
title_full_unstemmed Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
title_sort Triple-Decker [Cp*Fe(C8H6)Fe(C8H7)]
dc.creator.none.fl_str_mv Álvarez-Fernández, Alejandra|||0000-0002-1906-0180
Briansó, José Luis
Piniella, J. Francesc|||0000-0002-0552-6285
Farran José, Joan|||0000-0002-5933-1176
Manríquez, Juan M.
Chávez, Ivonne
Oelckers, Beatriz
Molins Grau, Elies|||0000-0003-1012-0551
Miravitlles Torras, Carles
author Álvarez-Fernández, Alejandra|||0000-0002-1906-0180
author_facet Álvarez-Fernández, Alejandra|||0000-0002-1906-0180
Briansó, José Luis
Piniella, J. Francesc|||0000-0002-0552-6285
Farran José, Joan|||0000-0002-5933-1176
Manríquez, Juan M.
Chávez, Ivonne
Oelckers, Beatriz
Molins Grau, Elies|||0000-0003-1012-0551
Miravitlles Torras, Carles
author_role author
author2 Briansó, José Luis
Piniella, J. Francesc|||0000-0002-0552-6285
Farran José, Joan|||0000-0002-5933-1176
Manríquez, Juan M.
Chávez, Ivonne
Oelckers, Beatriz
Molins Grau, Elies|||0000-0003-1012-0551
Miravitlles Torras, Carles
author2_role author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Cristal·lografia
Crystallography
topic Cristal·lografia
Crystallography
description The title compound [2(1,2,3,3a,6a-ƞ)pentalene]-[l(ƞ5)-pentamethylcyclopentadienyl]diiron, [Fe2(C8H7)-(C10H15)(C8H6)], has a metallocenic structure with the two pentalene ligands adopting an eclipsed conformation. In the central pentalene ligand, all the peripheral bonds are of similar length whereas the bridge bond is longer; there are two significantly different Fe-C distances, i.e. a mean value of 2.121(3)A for the Fe-Cbridge distances and a mean value of 2.028(3)A for the distances from the Fe atoms to all other Catoms. In the terminal pentalene ligand, the C-C and C-Fe distances in the ring bonded to the Fe atom are all similar.
publishDate 1996
dc.date.none.fl_str_mv 1
1996-01-01
1996
1996-01-01
dc.type.none.fl_str_mv Article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://ddd.uab.cat/record/27737
https://dx.doi.org/urn:doi:10.1107/S0108270196008037
url https://ddd.uab.cat/record/27737
https://dx.doi.org/urn:doi:10.1107/S0108270196008037
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
https://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Dipòsit Digital de Documents de la UAB
instname:Universitat Autònoma de Barcelona
instname_str Universitat Autònoma de Barcelona
reponame_str Dipòsit Digital de Documents de la UAB
collection Dipòsit Digital de Documents de la UAB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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