Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2

<p> The sustainable utilization of available feedstock materials for preparing valuable compounds holds great promise to revolutionize approaches in organic synthesis. In this regard, the implementation of abundant and inexpensive carbon dioxide (CO<sub>2</sub>) as a C1 building bl...

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Autores: Juliá-Hernández, Francisco, Gaydou, Morgane, Serrano, Eloisa, van Gemmeren, Manuel, Martin, Ruben
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305738
Acceso en línea:http://hdl.handle.net/2072/305738
https://doi.org/10.1007/s41061-016-0045-z
Access Level:acceso abierto
Palabra clave:Nickel
Iron
CO2 Carboxylation
Unsaturated hydrocarbons
Catalysis
Carboxylic acids
Cross-coupling
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spelling Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2Juliá-Hernández, FranciscoGaydou, MorganeSerrano, Eloisavan Gemmeren, ManuelMartin, RubenNickelIronCO2 CarboxylationUnsaturated hydrocarbonsCatalysisCarboxylic acidsCross-coupling<p> The sustainable utilization of available feedstock materials for preparing valuable compounds holds great promise to revolutionize approaches in organic synthesis. In this regard, the implementation of abundant and inexpensive carbon dioxide (CO<sub>2</sub>) as a C1 building block has recently attracted considerable attention. Among the different alternatives in CO<sub>2</sub> fixation, the preparation of carboxylic acids, relevant motifs in pharmaceuticals and agrochemicals, is particularly appealing, thus providing a rapid and unconventional entry to building blocks that are typically prepared via waste-producing protocols. While significant advances have been realized, the utilization of simple unsaturated hydrocarbons as coupling partners in carboxylation events is undoubtedly of utmost academic and industrial relevance, as two available feedstock materials can be combined in a catalytic fashion. This review article aims to describe the main achievements on the direct carboxylation of unsaturated hydrocarbons with CO<sub>2</sub> by using cheap and available Ni or Fe catalytic species.</p>Springer2016info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/2072/305738https://doi.org/10.1007/s41061-016-0045-zRECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésEuropean Research Council (ERC-277883)MINECO (CTQ2015-65496-RSevero Ochoa Excellence Accreditation 2014-2018Cellex FoundatioEuropean Research Council (ERC-277883), MINECO (CTQ2015-65496-R & Severo Ochoa Excellence Accreditation 2014-2018, SEV-2013-0319) and Cellex FoundatiTopics in Current Chemistryinfo:eu-repo/grantAgreement/ERC/FP7/277883MINECO (CTQ2015-65496-RSevero Ochoa Excellence2016 Springer International Publishing AG. Part of Springer Nature.info:eu-repo/semantics/openAccessoai:recercat.cat:2072/3057382026-05-29T05:05:01Z
dc.title.none.fl_str_mv Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
title Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
spellingShingle Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
Juliá-Hernández, Francisco
Nickel
Iron
CO2 Carboxylation
Unsaturated hydrocarbons
Catalysis
Carboxylic acids
Cross-coupling
title_short Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
title_full Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
title_fullStr Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
title_full_unstemmed Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
title_sort Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
dc.creator.none.fl_str_mv Juliá-Hernández, Francisco
Gaydou, Morgane
Serrano, Eloisa
van Gemmeren, Manuel
Martin, Ruben
author Juliá-Hernández, Francisco
author_facet Juliá-Hernández, Francisco
Gaydou, Morgane
Serrano, Eloisa
van Gemmeren, Manuel
Martin, Ruben
author_role author
author2 Gaydou, Morgane
Serrano, Eloisa
van Gemmeren, Manuel
Martin, Ruben
author2_role author
author
author
author
dc.subject.none.fl_str_mv Nickel
Iron
CO2 Carboxylation
Unsaturated hydrocarbons
Catalysis
Carboxylic acids
Cross-coupling
topic Nickel
Iron
CO2 Carboxylation
Unsaturated hydrocarbons
Catalysis
Carboxylic acids
Cross-coupling
description <p> The sustainable utilization of available feedstock materials for preparing valuable compounds holds great promise to revolutionize approaches in organic synthesis. In this regard, the implementation of abundant and inexpensive carbon dioxide (CO<sub>2</sub>) as a C1 building block has recently attracted considerable attention. Among the different alternatives in CO<sub>2</sub> fixation, the preparation of carboxylic acids, relevant motifs in pharmaceuticals and agrochemicals, is particularly appealing, thus providing a rapid and unconventional entry to building blocks that are typically prepared via waste-producing protocols. While significant advances have been realized, the utilization of simple unsaturated hydrocarbons as coupling partners in carboxylation events is undoubtedly of utmost academic and industrial relevance, as two available feedstock materials can be combined in a catalytic fashion. This review article aims to describe the main achievements on the direct carboxylation of unsaturated hydrocarbons with CO<sub>2</sub> by using cheap and available Ni or Fe catalytic species.</p>
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/305738
https://doi.org/10.1007/s41061-016-0045-z
url http://hdl.handle.net/2072/305738
https://doi.org/10.1007/s41061-016-0045-z
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv European Research Council (ERC-277883)
MINECO (CTQ2015-65496-R
Severo Ochoa Excellence Accreditation 2014-2018
Cellex Foundatio
European Research Council (ERC-277883), MINECO (CTQ2015-65496-R & Severo Ochoa Excellence Accreditation 2014-2018, SEV-2013-0319) and Cellex Foundati
Topics in Current Chemistry
info:eu-repo/grantAgreement/ERC/FP7/277883
MINECO (CTQ2015-65496-R
Severo Ochoa Excellence
dc.rights.none.fl_str_mv 2016 Springer International Publishing AG. Part of Springer Nature.
info:eu-repo/semantics/openAccess
rights_invalid_str_mv 2016 Springer International Publishing AG. Part of Springer Nature.
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Springer
publisher.none.fl_str_mv Springer
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.812429

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