Ni-catalyzed Reductive Carboxylation of Cyclopropyl Motifs with CO2
<div> <p> A Ni-catalyzed reductive carboxylation technique en route to cyclopropyl carboxylic acids has been developed. This user-friendly and mild transformation operates at atmospheric pressure of CO <sub>2 </sub>and utilizes either organic halides or alkene precursors, thu...
| Autores: | , |
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| Formato: | artículo |
| Fecha de publicación: | 2016 |
| País: | España |
| Recursos: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305895 |
| Acesso em linha: | http://hdl.handle.net/2072/305895 https://doi.org/10.1055/s-0035-1560439 |
| Access Level: | acceso abierto |
| Palavra-chave: | Nickel, carboxylation cross-coupling carbon dioxide catalysis |
| Resumo: | <div> <p> A Ni-catalyzed reductive carboxylation technique en route to cyclopropyl carboxylic acids has been developed. This user-friendly and mild transformation operates at atmospheric pressure of CO <sub>2 </sub>and utilizes either organic halides or alkene precursors, thus representing the first example of catalytic reductive carboxylation of secondary counterparts lacking adjacent p-components.</p> </div> <p> </p> |
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