Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
<p> A user-friendly Ni-catalyzed reductive carboxylation of benzylic C−N bonds with CO<sub>2</sub> is described. This procedure outperforms state-of-the-art techniques for the carboxylation of benzyl electrophiles by avoiding commonly observed parasitic pathways, such as...
| Autores: | , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2016 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305934 |
| Acceso en línea: | http://hdl.handle.net/2072/305934 https://doi.org/10.1002/anie.201600697 |
| Access Level: | acceso abierto |
| Palabra clave: | Nickel C–N activation Reductive coupling Carboxylation Catalysis |
| Sumario: | <p> A user-friendly Ni-catalyzed reductive carboxylation of benzylic C−N bonds with CO<sub>2</sub> is described. This procedure outperforms state-of-the-art techniques for the carboxylation of benzyl electrophiles by avoiding commonly observed parasitic pathways, such as homodimerization or β-hydride elimination, thus leading to new knowledge in cross-electrophile reactions.</p> |
|---|