Ni- and Fe-catalyzed Carboxylation of Unsaturated Hydrocarbons with CO2
<p> The sustainable utilization of available feedstock materials for preparing valuable compounds holds great promise to revolutionize approaches in organic synthesis. In this regard, the implementation of abundant and inexpensive carbon dioxide (CO<sub>2</sub>) as a C1 building bl...
| Autores: | , , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2016 |
| País: | España |
| Recursos: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305738 |
| Acesso em linha: | http://hdl.handle.net/2072/305738 https://doi.org/10.1007/s41061-016-0045-z |
| Access Level: | acceso abierto |
| Palavra-chave: | Nickel Iron CO2 Carboxylation Unsaturated hydrocarbons Catalysis Carboxylic acids Cross-coupling |
| Resumo: | <p> The sustainable utilization of available feedstock materials for preparing valuable compounds holds great promise to revolutionize approaches in organic synthesis. In this regard, the implementation of abundant and inexpensive carbon dioxide (CO<sub>2</sub>) as a C1 building block has recently attracted considerable attention. Among the different alternatives in CO<sub>2</sub> fixation, the preparation of carboxylic acids, relevant motifs in pharmaceuticals and agrochemicals, is particularly appealing, thus providing a rapid and unconventional entry to building blocks that are typically prepared via waste-producing protocols. While significant advances have been realized, the utilization of simple unsaturated hydrocarbons as coupling partners in carboxylation events is undoubtedly of utmost academic and industrial relevance, as two available feedstock materials can be combined in a catalytic fashion. This review article aims to describe the main achievements on the direct carboxylation of unsaturated hydrocarbons with CO<sub>2</sub> by using cheap and available Ni or Fe catalytic species.</p> |
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