A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage

<p> A Ni/Cu-catalyzed silylation of unactivated C&ndash;O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol a...

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Detalles Bibliográficos
Autores: Zarate, Cayetana, Martin, Ruben
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305836
Acceso en línea:http://hdl.handle.net/2072/305836
https://doi.org/10.1021/ja412107b
Access Level:acceso abierto
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spelling A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O CleavageZarate, CayetanaMartin, Ruben<p> A Ni/Cu-catalyzed silylation of unactivated C&ndash;O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp<sup>2</sup>)<i>&minus;</i>O and even C(sp<sup>3</sup>)&ndash;O bonds with similar efficiency.</p>Journal of the American Chemical Society,2014info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/2072/305836https://doi.org/10.1021/ja412107bRECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésICIQERCMICINNICIQ Foundation, the European Research Council (ERC-277883) and MICINN (CTQ2012-34054)J. Am. Chem. Soc.info:eu-repo/grantAgreement/ERC/FP7/277883(CTQ2012-34054)© 2014 American Chemical Societyinfo:eu-repo/semantics/openAccessoai:recercat.cat:2072/3058362026-05-29T05:05:01Z
dc.title.none.fl_str_mv A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
title A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
spellingShingle A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
Zarate, Cayetana
title_short A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
title_full A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
title_fullStr A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
title_full_unstemmed A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
title_sort A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
dc.creator.none.fl_str_mv Zarate, Cayetana
Martin, Ruben
author Zarate, Cayetana
author_facet Zarate, Cayetana
Martin, Ruben
author_role author
author2 Martin, Ruben
author2_role author
description <p> A Ni/Cu-catalyzed silylation of unactivated C&ndash;O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp<sup>2</sup>)<i>&minus;</i>O and even C(sp<sup>3</sup>)&ndash;O bonds with similar efficiency.</p>
publishDate 2014
dc.date.none.fl_str_mv 2014
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/305836
https://doi.org/10.1021/ja412107b
url http://hdl.handle.net/2072/305836
https://doi.org/10.1021/ja412107b
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv ICIQ
ERC
MICINN
ICIQ Foundation, the European Research Council (ERC-277883) and MICINN (CTQ2012-34054)
J. Am. Chem. Soc.
info:eu-repo/grantAgreement/ERC/FP7/277883
(CTQ2012-34054)
dc.rights.none.fl_str_mv © 2014 American Chemical Society
info:eu-repo/semantics/openAccess
rights_invalid_str_mv © 2014 American Chemical Society
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Journal of the American Chemical Society,
publisher.none.fl_str_mv Journal of the American Chemical Society,
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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