Ipso-Borylation of Aryl Ethers via Ni-catalyzed C–OMe Cleavage
<p> A Ni-catalyzed <i>ipso-</i>borylation of aryl ethers via C(sp<sup>2</sup>)–OMe and C(sp<sup>3</sup>)–OMe cleavage is described. The transformation is characterized by its wide substrate scope under mild conditions and an exquisite div...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305838 |
| Acceso en línea: | http://hdl.handle.net/2072/305838 https://doi.org/10.1021/jacs.5b03955 |
| Access Level: | acceso abierto |
| Sumario: | <p> A Ni-catalyzed <i>ipso-</i>borylation of aryl ethers via C(sp<sup>2</sup>)–OMe and C(sp<sup>3</sup>)–OMe cleavage is described. The transformation is characterized by its wide substrate scope under mild conditions and an exquisite divergence in site selectivity that can be easily switched by selecting the appropriate boron reagent.</p> |
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