Ni-catalyzed Mild Chemo-, Regio- and Diastereoselective Bond- Formation via Proximal C–C Cleavage of Benzocyclobutenones
<p> The first catalytic intermolecular proximal C1<img alt="[BOND]" src="http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif" />C2 cleavage of benzocyclobutenones (BCB) without prior carbonyl activation or employing noble metals has been developed...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305844 |
| Acceso en línea: | http://hdl.handle.net/2072/305844 https://doi.org/10.1002/anie.201503461 |
| Access Level: | acceso abierto |
| Sumario: | <p> The first catalytic intermolecular proximal C1<img alt="[BOND]" src="http://onlinelibrarystatic.wiley.com/undisplayable_characters/00f8ff.gif" />C2 cleavage of benzocyclobutenones (BCB) without prior carbonyl activation or employing noble metals has been developed. This protocol operates at room temperature and is characterized by an exquisite chemo-, regio- and diastereoselectivity profile, constituting a unique platform for preparing an array of elusive carbocyclic skeletons.</p> |
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