A Mild Synergistic Ni/Cu-Catalyzed Silylation via C–O Cleavage
<p> A Ni/Cu-catalyzed silylation of unactivated C–O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol a...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 2014 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/305836 |
| Acceso en línea: | http://hdl.handle.net/2072/305836 https://doi.org/10.1021/ja412107b |
| Access Level: | acceso abierto |
| Sumario: | <p> A Ni/Cu-catalyzed silylation of unactivated C–O electrophiles derived from phenols or benzyl alcohols is described. This transformation is characterized by its wide scope and mild conditions, providing a direct access to synthetically versatile silylated compounds. The protocol allows for the coupling of C(sp<sup>2</sup>)<i>−</i>O and even C(sp<sup>3</sup>)–O bonds with similar efficiency.</p> |
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