Photoflexoelectric effect in halide perovskites

Harvesting environmental energy to generate electricity is a key scientific and technological endeavour of our time. Photovoltaic conversion and electromechanical transduction are two common energy-harvesting mechanisms based on, respectively, semiconducting junctions and piezoelectric insulators. H...

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Detalles Bibliográficos
Autores: Shu, Longlong|||0000-0002-7121-1652, Ke, Shanming|||0000-0003-3204-1416, Fei, Linfeng|||0000-0001-7329-0019, Huang, Wenbin, Wang, Zhiguo|||0000-0001-9409-1334, Gong, Jinhui, Jiang, Xiaoning, Wang, Li, Li, Fei|||0000-0002-4572-0322, Lei, Shuijin, Rao, Zhenggang, Zhou, Yangbo, Zheng, Ren-Kui, Yao, Xi, Wang, Yu, Stengel, Massimiliano|||0000-0003-4175-3888, Catalan, Gustau|||0000-0003-0214-4828
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:224240
Acceso en línea:https://ddd.uab.cat/record/224240
https://dx.doi.org/urn:doi:10.1038/s41563-020-0659-y
Access Level:acceso abierto
Palabra clave:Electromechanical transduction
Environmental energy
Flexoelectricity
Generate electricity
Halide perovskites
Orders of magnitude
Photovoltaic conversion
Photovoltaic materials
Descripción
Sumario:Harvesting environmental energy to generate electricity is a key scientific and technological endeavour of our time. Photovoltaic conversion and electromechanical transduction are two common energy-harvesting mechanisms based on, respectively, semiconducting junctions and piezoelectric insulators. However, the different material families on which these transduction phenomena are based complicate their integration into single devices. Here we demonstrate that halide perovskites, a family of highly efficient photovoltaic materials, display a photoflexoelectric effect whereby, under a combination of illumination and oscillation driven by a piezoelectric actuator, they generate orders of magnitude higher flexoelectricity than in the dark. We also show that photoflexoelectricity is not exclusive to halides but a general property of semiconductors that potentially enables simultaneous electromechanical and photovoltaic transduction and harvesting in unison from multiple energy inputs.