Photoflexoelectric effect in halide perovskites

Harvesting environmental energy to generate electricity is a key scientific and technological endeavour of our time. Photovoltaic conversion and electromechanical transduction are two common energy-harvesting mechanisms based on, respectively, semiconducting junctions and piezoelectric insulators. H...

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Detalhes bibliográficos
Autores: Shu, Longlong|||0000-0002-7121-1652, Ke, Shanming|||0000-0003-3204-1416, Fei, Linfeng|||0000-0001-7329-0019, Huang, Wenbin, Wang, Zhiguo|||0000-0001-9409-1334, Gong, Jinhui, Jiang, Xiaoning, Wang, Li, Li, Fei|||0000-0002-4572-0322, Lei, Shuijin, Rao, Zhenggang, Zhou, Yangbo, Zheng, Ren-Kui, Yao, Xi, Wang, Yu, Stengel, Massimiliano|||0000-0003-4175-3888, Catalan, Gustau|||0000-0003-0214-4828
Tipo de documento: artigo
Data de publicação:2020
País:España
Recursos:Universitat Autònoma de Barcelona
Repositório:Dipòsit Digital de Documents de la UAB
Idioma:inglês
OAI Identifier:oai:ddd.uab.cat:224240
Acesso em linha:https://ddd.uab.cat/record/224240
https://dx.doi.org/urn:doi:10.1038/s41563-020-0659-y
Access Level:Acceso aberto
Palavra-chave:Electromechanical transduction
Environmental energy
Flexoelectricity
Generate electricity
Halide perovskites
Orders of magnitude
Photovoltaic conversion
Photovoltaic materials
Descrição
Resumo:Harvesting environmental energy to generate electricity is a key scientific and technological endeavour of our time. Photovoltaic conversion and electromechanical transduction are two common energy-harvesting mechanisms based on, respectively, semiconducting junctions and piezoelectric insulators. However, the different material families on which these transduction phenomena are based complicate their integration into single devices. Here we demonstrate that halide perovskites, a family of highly efficient photovoltaic materials, display a photoflexoelectric effect whereby, under a combination of illumination and oscillation driven by a piezoelectric actuator, they generate orders of magnitude higher flexoelectricity than in the dark. We also show that photoflexoelectricity is not exclusive to halides but a general property of semiconductors that potentially enables simultaneous electromechanical and photovoltaic transduction and harvesting in unison from multiple energy inputs.