Strain-gradient-induced modulation of photovoltaic efficiency

In this paper, we show that strain gradients can greatly affect the total photovoltaic efficiency of perovskite solar cells. By adding the flexophotovoltaic effect on top of the standard photovoltaic effect of semiconductor junctions, the total output of perovskite photovoltaic devices can be either...

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Detalles Bibliográficos
Autores: Wang, Zhiguo|||0000-0001-9409-1334, Zhong, Hongqiang, Liu, Zhiyong|||0000-0002-6930-5879, Hu, Xiaotian, Shu, Longlong|||0000-0002-7121-1652, Catalan, Gustau|||0000-0003-0214-4828
Tipo de recurso: artículo
Fecha de publicación:2025
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:310026
Acceso en línea:https://ddd.uab.cat/record/310026
https://dx.doi.org/urn:doi:10.1016/j.matt.2024.11.024
Access Level:acceso abierto
Palabra clave:Flexoelectricity
Photovoltaic effect
Flexophotovoltaic effect
Halide perovskites
Solar cells
Strain gradient
Photovoltaic efficiency
Strain engineering
Descripción
Sumario:In this paper, we show that strain gradients can greatly affect the total photovoltaic efficiency of perovskite solar cells. By adding the flexophotovoltaic effect on top of the standard photovoltaic effect of semiconductor junctions, the total output of perovskite photovoltaic devices can be either completely suppressed or greatly enhanced, depending on the relative sign of the strain gradient with respect to the semiconductor junction polarity. The results thus indicate that, whether as a threat to efficiency or as a means to enhance it, strain gradients can greatly affect the performance of perovskite solar cells, and flexoelectric engineering is thus an indispensable step in the pursuit of maximal photovoltaic efficiency.