Crystal and Molecular Structure of 2-Aminoacetophenone- N(3)-dimethylthiosemicarbazone
Condensation of N(3)-dimethylthiosemicarbazide with 2-aminoacetophenone in anhydrous ethanol produces 2-aminoacetophenone-N(3)-dimethylthiosemicarbazone, 1, which is planar withthe S1 and N1 atoms in a synconformation. The amino group forms abifurcated intramolecular hydrogen bond with the sulfur an...
| Authors: | , , , |
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| Format: | article |
| Status: | Published version |
| Publication Date: | 2002 |
| Country: | México |
| Institution: | Universidad Nacional Autónoma de México |
| Repository: | Redalyc-UNAM |
| OAI Identifier: | oai:redalyc.org:47546313 |
| Online Access: | https://www.redalyc.org/articulo.oa?id=47546313 |
| Access Level: | Open access |
| Keyword: | Química Ray Crystal structure Thiosemicarbazones |
| Summary: | Condensation of N(3)-dimethylthiosemicarbazide with 2-aminoacetophenone in anhydrous ethanol produces 2-aminoacetophenone-N(3)-dimethylthiosemicarbazone, 1, which is planar withthe S1 and N1 atoms in a synconformation. The amino group forms abifurcated intramolecular hydrogen bond with the sulfur and theimine nitrogen, and an intermolecular hydrogen bond with the thionesulfur of a second molecule. |
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