Crystal and Molecular Structure of 2-Aminoacetophenone- N(3)-dimethylthiosemicarbazone
Condensation of N(3)-dimethylthiosemicarbazide with 2-aminoacetophenone in anhydrous ethanol produces 2-aminoacetophenone-N(3)-dimethylthiosemicarbazone, 1, which is planar withthe S1 and N1 atoms in a synconformation. The amino group forms abifurcated intramolecular hydrogen bond with the sulfur an...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2002 |
| País: | México |
| Institución: | Universidad Nacional Autónoma de México |
| Repositorio: | Redalyc-UNAM |
| OAI Identifier: | oai:redalyc.org:47546313 |
| Acceso en línea: | https://www.redalyc.org/articulo.oa?id=47546313 |
| Access Level: | acceso abierto |
| Palabra clave: | Química Ray Crystal structure Thiosemicarbazones |
| Sumario: | Condensation of N(3)-dimethylthiosemicarbazide with 2-aminoacetophenone in anhydrous ethanol produces 2-aminoacetophenone-N(3)-dimethylthiosemicarbazone, 1, which is planar withthe S1 and N1 atoms in a synconformation. The amino group forms abifurcated intramolecular hydrogen bond with the sulfur and theimine nitrogen, and an intermolecular hydrogen bond with the thionesulfur of a second molecule. |
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