Crystal and Molecular Structure of 2-Benzoylpyridine N4-p-methoxyphenylthiosemicarbazone

2-benzoylpyridine N4-p-methoxyphenylthiosemicarbazone,HBz4pMeOPh, crystallizes with a Z arrangement of N1 andN2 with respect to C7-N2, which allows for the N3-H3A...N1 hydrogenbond and a six-membered ring. In addition, a 5-membered ringinvolving a second hydrogen bond, N4-H4A...N2 results in the N2a...

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Detalles Bibliográficos
Autores: Rubén A. Toscano, Jesús Valdés Martínez, Douglas X. West, Jack J. Ingram III, Gordon A. Bain
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2000
País:México
Institución:Universidad Nacional Autónoma de México
Repositorio:Redalyc-UNAM
OAI Identifier:oai:redalyc.org:47544216
Acceso en línea:https://www.redalyc.org/articulo.oa?id=47544216
Access Level:acceso abierto
Palabra clave:Química
crystal structure
thiosemicarbazones
Descripción
Sumario:2-benzoylpyridine N4-p-methoxyphenylthiosemicarbazone,HBz4pMeOPh, crystallizes with a Z arrangement of N1 andN2 with respect to C7-N2, which allows for the N3-H3A...N1 hydrogenbond and a six-membered ring. In addition, a 5-membered ringinvolving a second hydrogen bond, N4-H4A...N2 results in the N2and S1 E conformation with respect to N3-C8. Intramolecular CH...O and C-H...S hydrogen bonds create supramolecular chains.