Crystal and Molecular Structure of 2-Benzoylpyridine N4-p-methoxyphenylthiosemicarbazone
2-benzoylpyridine N4-p-methoxyphenylthiosemicarbazone,HBz4pMeOPh, crystallizes with a Z arrangement of N1 andN2 with respect to C7-N2, which allows for the N3-H3A...N1 hydrogenbond and a six-membered ring. In addition, a 5-membered ringinvolving a second hydrogen bond, N4-H4A...N2 results in the N2a...
| Autores: | , , , , |
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| Tipo de documento: | artigo |
| Estado: | Versão publicada |
| Data de publicação: | 2000 |
| País: | México |
| Recursos: | Universidad Nacional Autónoma de México |
| Repositório: | Redalyc-UNAM |
| OAI Identifier: | oai:redalyc.org:47544216 |
| Acesso em linha: | https://www.redalyc.org/articulo.oa?id=47544216 |
| Access Level: | Acceso aberto |
| Palavra-chave: | Química crystal structure thiosemicarbazones |
| Resumo: | 2-benzoylpyridine N4-p-methoxyphenylthiosemicarbazone,HBz4pMeOPh, crystallizes with a Z arrangement of N1 andN2 with respect to C7-N2, which allows for the N3-H3A...N1 hydrogenbond and a six-membered ring. In addition, a 5-membered ringinvolving a second hydrogen bond, N4-H4A...N2 results in the N2and S1 E conformation with respect to N3-C8. Intramolecular CH...O and C-H...S hydrogen bonds create supramolecular chains. |
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