Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst

This is the peer reviewed version of the following article: Chemistry: A European Journal 23.69 (2017): 17478 –17481, which has been published in final form at http://doi.org/10.1002/chem.201705019. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions fo...

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Detalles Bibliográficos
Autores: Jarava-Barrera, Carlos, Parra, Alejandro, Amenós, Laura, Arroyo, Ana, Tortosa Manzanares, Mariola
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/680854
Acceso en línea:http://hdl.handle.net/10486/680854
https://dx.doi.org/10.1002/chem.201705019
Access Level:acceso abierto
Palabra clave:allenes
boron
copper
epoxides
stereoselective synthesis
Química
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spelling Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalystJarava-Barrera, CarlosParra, AlejandroAmenós, LauraArroyo, AnaTortosa Manzanares, Mariolaallenesboroncopperepoxidesstereoselective synthesisQuímicaThis is the peer reviewed version of the following article: Chemistry: A European Journal 23.69 (2017): 17478 –17481, which has been published in final form at http://doi.org/10.1002/chem.201705019. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-ArchivingChiral α-allenols are prepared with high diastereocontrol through an unprecedented and spontaneous β-oxygen elimination of an α-epoxy vinyl boronate. Stochiometric experiments and DFT calculations support a dual role of the copper catalyst, which orchestrates the hydroboration and the syn-elimination stepThe European ResearchCouncil (ERC-337776) and MINECO (CTQ2016-78779-R) for financial support M.T.thanks MICINNfor a RyC contractWileyDepartamento de Química OrgánicaFacultad de Ciencias20172017-12-11research articlehttp://purl.org/coar/resource_type/c_2df8fbb1AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/680854https://dx.doi.org/10.1002/chem.201705019reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/6808542026-06-23T12:46:27Z
dc.title.none.fl_str_mv Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst
title Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst
spellingShingle Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst
Jarava-Barrera, Carlos
allenes
boron
copper
epoxides
stereoselective synthesis
Química
title_short Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst
title_full Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst
title_fullStr Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst
title_full_unstemmed Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst
title_sort Stereoselective traceless borylation–allenation of propargylic epoxides: dual role of the copper catalyst
dc.creator.none.fl_str_mv Jarava-Barrera, Carlos
Parra, Alejandro
Amenós, Laura
Arroyo, Ana
Tortosa Manzanares, Mariola
author Jarava-Barrera, Carlos
author_facet Jarava-Barrera, Carlos
Parra, Alejandro
Amenós, Laura
Arroyo, Ana
Tortosa Manzanares, Mariola
author_role author
author2 Parra, Alejandro
Amenós, Laura
Arroyo, Ana
Tortosa Manzanares, Mariola
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Química Orgánica
Facultad de Ciencias
dc.subject.none.fl_str_mv allenes
boron
copper
epoxides
stereoselective synthesis
Química
topic allenes
boron
copper
epoxides
stereoselective synthesis
Química
description This is the peer reviewed version of the following article: Chemistry: A European Journal 23.69 (2017): 17478 –17481, which has been published in final form at http://doi.org/10.1002/chem.201705019. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
publishDate 2017
dc.date.none.fl_str_mv 2017
2017-12-11
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/680854
https://dx.doi.org/10.1002/chem.201705019
url http://hdl.handle.net/10486/680854
https://dx.doi.org/10.1002/chem.201705019
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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