Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2

<p> A user-friendly Ni-catalyzed reductive carboxylation of benzylic C&minus;N bonds with CO<sub>2</sub> is described. This procedure outperforms state-of-the-art techniques for the carboxylation of benzyl electrophiles by avoiding commonly observed parasitic pathways, such as...

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Detalles Bibliográficos
Autores: Moragas, Toni, Gaydou, Morgane, Martin, Ruben
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305934
Acceso en línea:http://hdl.handle.net/2072/305934
https://doi.org/10.1002/anie.201600697
Access Level:acceso abierto
Palabra clave:Nickel
C–N activation
Reductive coupling
Carboxylation
Catalysis
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spelling Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2Moragas, ToniGaydou, MorganeMartin, RubenNickelC–N activationReductive couplingCarboxylationCatalysis<p> A user-friendly Ni-catalyzed reductive carboxylation of benzylic C&minus;N bonds with CO<sub>2</sub> is described. This procedure outperforms state-of-the-art techniques for the carboxylation of benzyl electrophiles by avoiding commonly observed parasitic pathways, such as homodimerization or &beta;-hydride elimination, thus leading to new knowledge in cross-electrophile reactions.</p>Wiley2016info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/2072/305934https://doi.org/10.1002/anie.201600697RECERCAT (Dipòsit de la Recerca de Catalunya)reponame:Recercat. Dipósit de la Recerca de Catalunyainstname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)InglésICIQ foundation v the European Research CouncilMINECOSevero Ochoa Excellence AccreditationEuropean UnionEuropean Research Council (ERC-277883)MINECO (CTQ2012-34054) severo ochoa SEV-2013-0319Angew. Chem. Int.info:eu-repo/grantAgreement/ERC/FP7/277883CTQ2012-34054SEV-2013-0319)© 1999 - 2016 John Wiley & Sons, Inc.info:eu-repo/semantics/openAccessoai:recercat.cat:2072/3059342026-05-29T05:05:01Z
dc.title.none.fl_str_mv Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
title Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
spellingShingle Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
Moragas, Toni
Nickel
C–N activation
Reductive coupling
Carboxylation
Catalysis
title_short Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
title_full Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
title_fullStr Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
title_full_unstemmed Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
title_sort Nickel-Catalyzed Carboxylation of Benzylic C−N Bonds with CO2
dc.creator.none.fl_str_mv Moragas, Toni
Gaydou, Morgane
Martin, Ruben
author Moragas, Toni
author_facet Moragas, Toni
Gaydou, Morgane
Martin, Ruben
author_role author
author2 Gaydou, Morgane
Martin, Ruben
author2_role author
author
dc.subject.none.fl_str_mv Nickel
C–N activation
Reductive coupling
Carboxylation
Catalysis
topic Nickel
C–N activation
Reductive coupling
Carboxylation
Catalysis
description <p> A user-friendly Ni-catalyzed reductive carboxylation of benzylic C&minus;N bonds with CO<sub>2</sub> is described. This procedure outperforms state-of-the-art techniques for the carboxylation of benzyl electrophiles by avoiding commonly observed parasitic pathways, such as homodimerization or &beta;-hydride elimination, thus leading to new knowledge in cross-electrophile reactions.</p>
publishDate 2016
dc.date.none.fl_str_mv 2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/2072/305934
https://doi.org/10.1002/anie.201600697
url http://hdl.handle.net/2072/305934
https://doi.org/10.1002/anie.201600697
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv ICIQ foundation v the European Research Council
MINECO
Severo Ochoa Excellence Accreditation
European Union
European Research Council (ERC-277883)
MINECO (CTQ2012-34054) severo ochoa SEV-2013-0319
Angew. Chem. Int.
info:eu-repo/grantAgreement/ERC/FP7/277883
CTQ2012-34054
SEV-2013-0319)
dc.rights.none.fl_str_mv © 1999 - 2016 John Wiley & Sons, Inc.
info:eu-repo/semantics/openAccess
rights_invalid_str_mv © 1999 - 2016 John Wiley & Sons, Inc.
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv RECERCAT (Dipòsit de la Recerca de Catalunya)
reponame:Recercat. Dipósit de la Recerca de Catalunya
instname:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
instname_str Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
reponame_str Recercat. Dipósit de la Recerca de Catalunya
collection Recercat. Dipósit de la Recerca de Catalunya
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,81155

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