Optimization of a method to extract polysaccharides from white grape pomace by-products

The aim of this paper is to optimize a method to recover polysaccharides from white grape pomace (non-fermented), the main waste by-product of the food industry. Different conditions are tested and the polysaccharides extracted are analyzed by high performance size exclusion chromatography with refr...

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Detalles Bibliográficos
Autores: Canalejo, Diego, Guadalupe, Zenaida, Martínez Lapuente, Leticia, Ayestarán, Belén, Pérez-Magariño, Silvia
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2021
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/262108
Acceso en línea:http://hdl.handle.net/10261/262108
Access Level:acceso abierto
Palabra clave:Carbohydrates
Grape waste
Isolation
Polysaccharides rich in arabinose and galactose (PRAG)
Rhamnogalacturonan type II (RG-II)
Homogalacturonans (HG)
Glucosyl polysaccharides (GP)
Descripción
Sumario:The aim of this paper is to optimize a method to recover polysaccharides from white grape pomace (non-fermented), the main waste by-product of the food industry. Different conditions are tested and the polysaccharides extracted are analyzed by high performance size exclusion chromatography with refractive index detector (HPSEC-RID) and gas chromatography with mass detector (GC-MS). The extraction solvent did not show a significant effect on the polysaccharide extraction, acid pH yielded to higher efficiencies, and longer extraction times extracted more smaller polysaccharides (≤5.4 kg mol). The highest efficiencies were obtained with both solvents at pH 1 and 1:4 solid to liquid ratio. The optimum conditions selected (TA as solvent of extraction, 2.5 g L solvent concentration, pH = 1, 1:4 solid to liquid ratio, and 18 h of extraction time) allow the extraction of polysaccharides rich in arabinose and galactose, rhamnogalacturonans, homogalacturonans and glucosyl polysaccharides, under efficient and food-safe conditions.