Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid

[EN] This work reports on the successful development of biopolypropylene/mango peel flour (bioPP/MPF) composites using extrusion and injection molding processes. The compatibility between bioPP and MPF is improved through the use of PP-g-IA (3 phr) as a compatibilizer (which is prepared by reactive...

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Autores: Gómez-Caturla, Jaume|||0000-0001-8680-4509, Balart, Rafael|||0000-0001-5670-7126, Ivorra-Martinez, Juan|||0000-0001-8968-4899, Garcia-Garcia, Daniel|||0000-0002-2520-0186, Dominici, Franco, Puglia, Debora, Torre, Luigi
Tipo de recurso: artículo
Fecha de publicación:2022
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/199573
Acceso en línea:https://riunet.upv.es/handle/10251/199573
Access Level:acceso abierto
Palabra clave:Polymer composites
Biopolymers
Reinforcements
Mango peel flour
Compatibilization
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación
12.- Garantizar las pautas de consumo y de producción sostenibles
13.- Tomar medidas urgentes para combatir el cambio climático y sus efectos
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oai_identifier_str oai:riunet.upv.es:10251/199573
network_acronym_str ES
network_name_str España
repository_id_str
spelling Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic AcidGómez-Caturla, Jaume|||0000-0001-8680-4509Balart, Rafael|||0000-0001-5670-7126Ivorra-Martinez, Juan|||0000-0001-8968-4899Garcia-Garcia, Daniel|||0000-0002-2520-0186Dominici, FrancoPuglia, DeboraTorre, LuigiPolymer compositesBiopolymersReinforcementsMango peel flourCompatibilizationCIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación12.- Garantizar las pautas de consumo y de producción sostenibles13.- Tomar medidas urgentes para combatir el cambio climático y sus efectos[EN] This work reports on the successful development of biopolypropylene/mango peel flour (bioPP/MPF) composites using extrusion and injection molding processes. The compatibility between bioPP and MPF is improved through the use of PP-g-IA (3 phr) as a compatibilizer (which is prepared by reactive extrusion REX) and dicumyl peroxide (DCP) (1 phr) as a cross-linker. The mechanical, morphological, thermal, thermomechanical, chemical, colorimetric, water absorption, and flowability properties are characterized and analyzed. The results show that MPF (30 wt %) compatibilized with PP-g-IA and DCP increased the stiffness of bioPP in terms of Young¿s modulus values. Elongation at break also shows very promising results, with a maximum value of almost 30% for the bioPP/MPF/PP-g-IA/DCP sample. PP-g-IA and DCP seem to exert a synergetic effect. Thermal stability is also improved as a result of these additives, as well as crystallinity, which is increased due to an heterogeneous nucleation phenomenon, enhanced by a higher dispersion of MPF particles in the matrix. Moreover, the excellent mechanical results are verified in FESEM images, where a very narrow gap between the MPF particles and the bioPP matrix is appreciated.J.G.-C., R.B., J.I.-M., D.G.-G., F.D., D.P., and L.T. received funding from the grant PID2020-116496RB-C22 funded by MCIN/AEI/10.13039/501100011033 (Agencia estatal de Investigacion). J.G.-C., R.B., J.I.-M., D.G.-G., F.D., D.P., and L.T. also received funding from Generalitat Valenciana-GVA with grant number AICO/2021/025.American Chemical SocietyDepartamento de Ingeniería Mecánica y de Materiales Instituto Universitario de Investigación de Tecnología de los Materiales de la UPVEscuela Politécnica Superior de AlcoyGENERALITAT VALENCIANAAGENCIA ESTATAL DE INVESTIGACIONUniversitat Politècnica de ValènciaRepositorio Institucional de la Universitat Politècnica de València Riunet20222022-06-10journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/199573reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-116496RB-C22 OBTENCION DE NANOCOMPOSITES DE ORIGEN BIO A PARTIR DE RESIDUOS LIGNOCELULOSICOS PARA SU USO EN FILMS MULTICAPAGeneralitat Valenciana https://doi.org/10.13039/501100003359 AICO%2F2021%2F025 NUEVOS MATERIALES SOSTENIBLES DERIVADOS DE LA REVALORIZACIÓN DE RESIDUOS DE LA INDUSTRIA DE CÍTRICOS ¿ CitricNewLifeopen accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento (by)http://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1995732026-06-13T07:49:27Z
dc.title.none.fl_str_mv Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid
title Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid
spellingShingle Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid
Gómez-Caturla, Jaume|||0000-0001-8680-4509
Polymer composites
Biopolymers
Reinforcements
Mango peel flour
Compatibilization
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación
12.- Garantizar las pautas de consumo y de producción sostenibles
13.- Tomar medidas urgentes para combatir el cambio climático y sus efectos
title_short Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid
title_full Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid
title_fullStr Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid
title_full_unstemmed Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid
title_sort Biopolypropylene-Based Wood Plastic Composites Reinforced with Mango Peel Flour and Compatibilized with an Environmentally Friendly Copolymer from Itaconic Acid
dc.creator.none.fl_str_mv Gómez-Caturla, Jaume|||0000-0001-8680-4509
Balart, Rafael|||0000-0001-5670-7126
Ivorra-Martinez, Juan|||0000-0001-8968-4899
Garcia-Garcia, Daniel|||0000-0002-2520-0186
Dominici, Franco
Puglia, Debora
Torre, Luigi
author Gómez-Caturla, Jaume|||0000-0001-8680-4509
author_facet Gómez-Caturla, Jaume|||0000-0001-8680-4509
Balart, Rafael|||0000-0001-5670-7126
Ivorra-Martinez, Juan|||0000-0001-8968-4899
Garcia-Garcia, Daniel|||0000-0002-2520-0186
Dominici, Franco
Puglia, Debora
Torre, Luigi
author_role author
author2 Balart, Rafael|||0000-0001-5670-7126
Ivorra-Martinez, Juan|||0000-0001-8968-4899
Garcia-Garcia, Daniel|||0000-0002-2520-0186
Dominici, Franco
Puglia, Debora
Torre, Luigi
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Mecánica y de Materiales
 Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV
Escuela Politécnica Superior de Alcoy
GENERALITAT VALENCIANA
AGENCIA ESTATAL DE INVESTIGACION
Universitat Politècnica de València
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Polymer composites
Biopolymers
Reinforcements
Mango peel flour
Compatibilization
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación
12.- Garantizar las pautas de consumo y de producción sostenibles
13.- Tomar medidas urgentes para combatir el cambio climático y sus efectos
topic Polymer composites
Biopolymers
Reinforcements
Mango peel flour
Compatibilization
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
09.- Desarrollar infraestructuras resilientes, promover la industrialización inclusiva y sostenible, y fomentar la innovación
12.- Garantizar las pautas de consumo y de producción sostenibles
13.- Tomar medidas urgentes para combatir el cambio climático y sus efectos
description [EN] This work reports on the successful development of biopolypropylene/mango peel flour (bioPP/MPF) composites using extrusion and injection molding processes. The compatibility between bioPP and MPF is improved through the use of PP-g-IA (3 phr) as a compatibilizer (which is prepared by reactive extrusion REX) and dicumyl peroxide (DCP) (1 phr) as a cross-linker. The mechanical, morphological, thermal, thermomechanical, chemical, colorimetric, water absorption, and flowability properties are characterized and analyzed. The results show that MPF (30 wt %) compatibilized with PP-g-IA and DCP increased the stiffness of bioPP in terms of Young¿s modulus values. Elongation at break also shows very promising results, with a maximum value of almost 30% for the bioPP/MPF/PP-g-IA/DCP sample. PP-g-IA and DCP seem to exert a synergetic effect. Thermal stability is also improved as a result of these additives, as well as crystallinity, which is increased due to an heterogeneous nucleation phenomenon, enhanced by a higher dispersion of MPF particles in the matrix. Moreover, the excellent mechanical results are verified in FESEM images, where a very narrow gap between the MPF particles and the bioPP matrix is appreciated.
publishDate 2022
dc.date.none.fl_str_mv 2022
2022-06-10
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/199573
url https://riunet.upv.es/handle/10251/199573
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-116496RB-C22 OBTENCION DE NANOCOMPOSITES DE ORIGEN BIO A PARTIR DE RESIDUOS LIGNOCELULOSICOS PARA SU USO EN FILMS MULTICAPA
Generalitat Valenciana https://doi.org/10.13039/501100003359 AICO%2F2021%2F025 NUEVOS MATERIALES SOSTENIBLES DERIVADOS DE LA REVALORIZACIÓN DE RESIDUOS DE LA INDUSTRIA DE CÍTRICOS ¿ CitricNewLife
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300724

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