Antioxidant, hypotensive, and antidiabetic breakthroughs: Bromelain hydrolysis unlocks quinoa’s peptide potential - In silico and in vitro approach

This study integrates bioinformatics and experimental approaches to characterize bioactive peptides derived from quinoa 11S-globulin (Chenopodium quinoa Willd) hydrolyzedin silico by stem bromelain (EC3.4.22.32). A total of 109 peptides were generated, of which 14 sequences with more than five amino...

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Detalles Bibliográficos
Autores: Manzanilla-Valdez, María Lilibeth, Montaño, Sarita, Martínez-Villaluenga, Cristina, Zúñiga, Fernanda, Boesch, Christine, Hernández-Álvarez, Alan Javier
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2025
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/410095
Acceso en línea:http://hdl.handle.net/10261/410095
Access Level:acceso abierto
Palabra clave:Quinoa
Bromelain
Bioinformatics
11S globulin
Metabolic disorders
Molecular dynamic
Descripción
Sumario:This study integrates bioinformatics and experimental approaches to characterize bioactive peptides derived from quinoa 11S-globulin (Chenopodium quinoa Willd) hydrolyzedin silico by stem bromelain (EC3.4.22.32). A total of 109 peptides were generated, of which 14 sequences with more than five amino acids were selected based on molecular docking and dynamics simulations against key metabolic targets (ACE-I, DPP-IV, α-glucosidase, and lipoxygenase). NIYQIS and QDQHQKIR demonstrated the highest binding affinities and hydrogen-bonding interactions, with ADMET predictions confirming their non-toxic and bioavailable profiles. In vitro, NIYQIS showed the strongest inhibitory activity against ACE-I (53%), DPP-IV (16.36%) and exhibited the highest antioxidant capacity (ORAC: 0.75 μM TE/μM peptide). Conversely, QDQHQKIR demonstrated the highest α-amylase inhibition (18.43%) and Cu2+ chelation (40.4%), supporting its role in carbohydrate metabolism and metal-ion homeostasis. Overall, NIYQIS emerged as the most promising peptide, highlighting the potential of quinoa-derived peptides as functional ingredients to mitigate oxidative stress and metabolic disorders.