Molybdenum isotope systematics in subduction zones

This study presents Mo isotope data for arc lavas from different subduction zones that range between δ98/95Mo=−0.72 and +0.07‰. Heaviest isotope values are observed for the most slab fluid dominated samples. Isotopically lighter signatures are related to increasing relevance of terrigenous sediment...

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Detalles Bibliográficos
Autores: König, Stephan, Wille, Martin, Voegelin, Andrea, Schoenberg, Ronny
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/414671
Acceso en línea:http://hdl.handle.net/10261/414671
https://doi.org/10.1016/j.epsl.2016.04.033
Access Level:acceso abierto
Palabra clave:Mo isotopes
Molybdenum
Subduction
Arc
Slab fluid
Sediments
Descripción
Sumario:This study presents Mo isotope data for arc lavas from different subduction zones that range between δ98/95Mo=−0.72 and +0.07‰. Heaviest isotope values are observed for the most slab fluid dominated samples. Isotopically lighter signatures are related to increasing relevance of terrigenous sediment subduction and sediment melt components. Our observation complements previous conclusions that an isotopically heavy Mo fluid flux likely mirrors selective incorporation of isotopically light Mo in secondary minerals within the subducting slab. Analogue to this interpretation, low δ98/95Mo flux that coincides with terrigenous sediment subduction and sediment melting cannot be simply related to a recycled input signature. Instead, breakdown of the controlling secondary minerals during sediment melting may release the light component and lead to decreasing δ98/95Mo influx into subarc mantle sources. The natural range between slab dehydration and hydrous sediment melting may thus cause a large spread of δ98/95Mo in global subduction zone magmas.