Generation and ring opening of aziridineN-carbonyl radicals

Aziridine N-carbonyl radicals, generated by irradiating the corresponding S-oxalyl xanthates, undergo ring opening to give 2-isocyanato radicals, which can be trapped by an external olefin.

Detalhes bibliográficos
Autores: Heinrich, Markus R., Pérez-Martín, Inés, Zard, Samir Z.
Tipo de documento: artigo
Estado:Versión aceptada para publicación
Data de publicação:2005
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositório:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/211997
Acesso em linha:http://hdl.handle.net/10261/211997
Access Level:Acceso aberto
Palavra-chave:Generation
AziridineN-carbonyl radicals
Descrição
Resumo:Aziridine N-carbonyl radicals, generated by irradiating the corresponding S-oxalyl xanthates, undergo ring opening to give 2-isocyanato radicals, which can be trapped by an external olefin.