Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization

A method is proposed for the determination of alcohols and phenols based on their derivatization to benzoates and gas chromatography-gas phase molecular absorption spectrometry. All parameters affecting the derivatization reaction, such as the solvent, basic medium, benzoyl chloride and stirring tim...

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Bibliographic Details
Authors: Sanz-Vicente, I. [0000-0002-3906-4576], Cabredo, S. [0000-0002-8828-4700], Galbán, J. [0000-0002-8973-5104]
Format: article
Status:Published version
Publication Date:1998
Country:España
Institution:Universidad de La Rioja (UR)
Repository:RIUR. Repositorio Institucional de la Universidad de La Rioja
OAI Identifier:oai:portal.dialnet.es:doc/5bbc695bb750603269e819b6
Online Access:https://investigacion.unirioja.es/documentos/5bbc695bb750603269e819b6
Access Level:Open access
Keyword:Alcohols and phenols
Derivatization
Gas chromatography
Gas phase absorption spectrometry
UV-Vis detection
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spelling Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatizationSanz-Vicente, I. [0000-0002-3906-4576]Cabredo, S. [0000-0002-8828-4700]Galbán, J. [0000-0002-8973-5104]Alcohols and phenolsDerivatizationGas chromatographyGas phase absorption spectrometryUV-Vis detectionA method is proposed for the determination of alcohols and phenols based on their derivatization to benzoates and gas chromatography-gas phase molecular absorption spectrometry. All parameters affecting the derivatization reaction, such as the solvent, basic medium, benzoyl chloride and stirring time, were optimized. Chromatographic and instrumental conditions were also studied. Finally, a calibration study was performed and the results were compared to that obtained by the direct determination of the compounds.1998info:eu-repo/semantics/articleSubtype: Articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://investigacion.unirioja.es/documentos/5bbc695bb750603269e819b6reponame:RIUR. Repositorio Institucional de la Universidad de La Riojainstname:Universidad de La Rioja (UR)Inglésinfo:eu-repo/semantics/altIdentifier/doi/10.1007/BF02466647info:eu-repo/semantics/altIdentifier/wos/WOS:000078156800011info:eu-repo/semantics/altIdentifier/pissn/0009-5893Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization, 1998, vol. 48, núm. 7, pág. 542-547info:eu-repo/semantics/openAccessoai:portal.dialnet.es:doc/5bbc695bb750603269e819b62026-06-14T12:47:17Z
dc.title.none.fl_str_mv Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization
title Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization
spellingShingle Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization
Sanz-Vicente, I. [0000-0002-3906-4576]
Alcohols and phenols
Derivatization
Gas chromatography
Gas phase absorption spectrometry
UV-Vis detection
title_short Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization
title_full Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization
title_fullStr Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization
title_full_unstemmed Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization
title_sort Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization
dc.creator.none.fl_str_mv Sanz-Vicente, I. [0000-0002-3906-4576]
Cabredo, S. [0000-0002-8828-4700]
Galbán, J. [0000-0002-8973-5104]
author Sanz-Vicente, I. [0000-0002-3906-4576]
author_facet Sanz-Vicente, I. [0000-0002-3906-4576]
Cabredo, S. [0000-0002-8828-4700]
Galbán, J. [0000-0002-8973-5104]
author_role author
author2 Cabredo, S. [0000-0002-8828-4700]
Galbán, J. [0000-0002-8973-5104]
author2_role author
author
dc.subject.none.fl_str_mv Alcohols and phenols
Derivatization
Gas chromatography
Gas phase absorption spectrometry
UV-Vis detection
topic Alcohols and phenols
Derivatization
Gas chromatography
Gas phase absorption spectrometry
UV-Vis detection
description A method is proposed for the determination of alcohols and phenols based on their derivatization to benzoates and gas chromatography-gas phase molecular absorption spectrometry. All parameters affecting the derivatization reaction, such as the solvent, basic medium, benzoyl chloride and stirring time, were optimized. Chromatographic and instrumental conditions were also studied. Finally, a calibration study was performed and the results were compared to that obtained by the direct determination of the compounds.
publishDate 1998
dc.date.none.fl_str_mv 1998
dc.type.none.fl_str_mv info:eu-repo/semantics/article
Subtype: Article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://investigacion.unirioja.es/documentos/5bbc695bb750603269e819b6
url https://investigacion.unirioja.es/documentos/5bbc695bb750603269e819b6
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/semantics/altIdentifier/doi/10.1007/BF02466647
info:eu-repo/semantics/altIdentifier/wos/WOS:000078156800011
info:eu-repo/semantics/altIdentifier/pissn/0009-5893
Gas chromatography with ultraviolet-visible molecular absorption spectrometry detection: increasing sensitivity of the determination of alcohols and phenols by derivatization, 1998, vol. 48, núm. 7, pág. 542-547
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:RIUR. Repositorio Institucional de la Universidad de La Rioja
instname:Universidad de La Rioja (UR)
instname_str Universidad de La Rioja (UR)
reponame_str RIUR. Repositorio Institucional de la Universidad de La Rioja
collection RIUR. Repositorio Institucional de la Universidad de La Rioja
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,301603

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