Rheometric non-isothermal gelatinization kinetics of high hydrostatic pressure treated chickpea flour slurry

The effect of high hydrostatic pressure (HHP) as a function of treatment pressure (200, 400, 600 MPa), temperature at pressurization (10, 25, 50 C), and treatment time (5, 15, 25 min) on the subsequent temperature-induced gelatinization of chickpea flour (CF) slurry during non-isothermal heating fro...

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Detalles Bibliográficos
Autores: Álvarez, M. Dolores, Cuesta, Francisco Javier, Fuentes, Raúl, Canet, Wenceslao
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/171617
Acceso en línea:http://hdl.handle.net/10261/171617
Access Level:acceso abierto
Palabra clave:Activation energy
Gelatinization
High pressure treatment
Chickpea flour
Reaction kinetics
Elastic modulus
Descripción
Sumario:The effect of high hydrostatic pressure (HHP) as a function of treatment pressure (200, 400, 600 MPa), temperature at pressurization (10, 25, 50 C), and treatment time (5, 15, 25 min) on the subsequent temperature-induced gelatinization of chickpea flour (CF) slurry during non-isothermal heating from 25 to 95 C was investigated. Temperature-induced gelatinization was sensitive to the changes in pressure, temperature, and time during HHP pre-treatment. During heating, CF gelatinization kinetics from the cross-over of elastic modulus (G0) and viscous modulus (G00) to 95 C were considered for rate estimation. Zero-order reaction kinetics adequately described the CF gelatinization process. Structure development rate (dG'/dt) is described by two exponential functions with activation energies ranging from 51.2 to 577 and e129 to 539 kJ mol1 for downward and upward gelatinization curves, respectively. Changes in dG'/dt vs. temperature seem to be closely related to the degree of gelatinization induced by HHP pretreatment.