A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil

[EN] The use of epoxidized cottonseed oil (ECSO) as plasticizer for poly(vinyl chloride), PVC was studied. The plasticizer content was set to 70 phr and the optimum isothermal curing conditions were studied in the temperature range comprised between 160 ºC and 220 ºC with varying curing times in the...

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Autores: Carbonell Verdú, Alfredo, Garcia-Sanoguera, David|||0000-0002-1923-9519, Jorda-Vilaplana, Amparo, Sanchez-Nacher, Lourdes|||0000-0002-8627-4576, Balart, Rafael|||0000-0001-5670-7126
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/82834
Acceso en línea:https://riunet.upv.es/handle/10251/82834
Access Level:acceso abierto
Palabra clave:Mechanical properties
Plasticizer
Poly(vinyl chloride)
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
EXPRESION GRAFICA EN LA INGENIERIA
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spelling A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oilCarbonell Verdú, AlfredoGarcia-Sanoguera, David|||0000-0002-1923-9519Jorda-Vilaplana, AmparoSanchez-Nacher, Lourdes|||0000-0002-8627-4576Balart, Rafael|||0000-0001-5670-7126Mechanical propertiesPlasticizerPoly(vinyl chloride)CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICAEXPRESION GRAFICA EN LA INGENIERIA[EN] The use of epoxidized cottonseed oil (ECSO) as plasticizer for poly(vinyl chloride), PVC was studied. The plasticizer content was set to 70 phr and the optimum isothermal curing conditions were studied in the temperature range comprised between 160 ºC and 220 ºC with varying curing times in the 7.5 - 17.5 min range. The influence of the curing conditions on overall performance of cured plastisols was followed by the evolution of mechanical properties (tensile tests with measurements of tensile strength, elongation at break and modulus), change in colour, surface changes of fractured samples by scanning electron microscopy (SEM), thermal transitions by differential scanning calorimetry (DSC) and migration in n-hexane. The optimum mechanical features of cured plastisols are obtained for curing temperatures in the 190-220 ºC range. For these curing conditions, fractography analysis by SEM gives evidences of full curing process as no PVC particles and free plasticizer can be found.R. Balart wants to thank the Ministry of Economy and Competitiveness - MINECO (Ref: MAT2014-59242-C2-1-R) for funding support. L. Sanchez-Nacher wants to thank the "Conselleria d'Educacio, Cultura i Esport - Generalitat Valenciana" (reference number: GV/2014/008). A. Carbonell-Verdu wants to thank the Polytechnic University of Valencia for their financial support through an FPI grant.WileyDepartamento de Ingeniería GráficaDepartamento de Ingeniería Mecánica y de Materiales Instituto Universitario de Investigación de Tecnología de los Materiales de la UPVEscuela Politécnica Superior de AlcoyMinisterio de Economía y CompetitividadGeneralitat ValencianaRepositorio Institucional de la Universitat Politècnica de València Riunet20162016-07-15journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfapplication/pdfapplication/pdfhttps://riunet.upv.es/handle/10251/82834reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2014-59242-C2-1-R TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOSGeneralitat Valenciana https://doi.org/10.13039/501100003359 GV%2F2014%2F008open accesshttp://purl.org/coar/access_right/c_abf2Reserva de todos los derechoshttp://rightsstatements.org/vocab/InC/1.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/828342026-06-13T07:49:27Z
dc.title.none.fl_str_mv A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil
title A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil
spellingShingle A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil
Carbonell Verdú, Alfredo
Mechanical properties
Plasticizer
Poly(vinyl chloride)
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
EXPRESION GRAFICA EN LA INGENIERIA
title_short A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil
title_full A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil
title_fullStr A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil
title_full_unstemmed A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil
title_sort A new biobased plasticizer for poly(vinyl chloride) based on epoxidized cottonseed oil
dc.creator.none.fl_str_mv Carbonell Verdú, Alfredo
Garcia-Sanoguera, David|||0000-0002-1923-9519
Jorda-Vilaplana, Amparo
Sanchez-Nacher, Lourdes|||0000-0002-8627-4576
Balart, Rafael|||0000-0001-5670-7126
author Carbonell Verdú, Alfredo
author_facet Carbonell Verdú, Alfredo
Garcia-Sanoguera, David|||0000-0002-1923-9519
Jorda-Vilaplana, Amparo
Sanchez-Nacher, Lourdes|||0000-0002-8627-4576
Balart, Rafael|||0000-0001-5670-7126
author_role author
author2 Garcia-Sanoguera, David|||0000-0002-1923-9519
Jorda-Vilaplana, Amparo
Sanchez-Nacher, Lourdes|||0000-0002-8627-4576
Balart, Rafael|||0000-0001-5670-7126
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Gráfica
Departamento de Ingeniería Mecánica y de Materiales
 Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV
Escuela Politécnica Superior de Alcoy
Ministerio de Economía y Competitividad
Generalitat Valenciana
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Mechanical properties
Plasticizer
Poly(vinyl chloride)
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
EXPRESION GRAFICA EN LA INGENIERIA
topic Mechanical properties
Plasticizer
Poly(vinyl chloride)
CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA
EXPRESION GRAFICA EN LA INGENIERIA
description [EN] The use of epoxidized cottonseed oil (ECSO) as plasticizer for poly(vinyl chloride), PVC was studied. The plasticizer content was set to 70 phr and the optimum isothermal curing conditions were studied in the temperature range comprised between 160 ºC and 220 ºC with varying curing times in the 7.5 - 17.5 min range. The influence of the curing conditions on overall performance of cured plastisols was followed by the evolution of mechanical properties (tensile tests with measurements of tensile strength, elongation at break and modulus), change in colour, surface changes of fractured samples by scanning electron microscopy (SEM), thermal transitions by differential scanning calorimetry (DSC) and migration in n-hexane. The optimum mechanical features of cured plastisols are obtained for curing temperatures in the 190-220 ºC range. For these curing conditions, fractography analysis by SEM gives evidences of full curing process as no PVC particles and free plasticizer can be found.
publishDate 2016
dc.date.none.fl_str_mv 2016
2016-07-15
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/82834
url https://riunet.upv.es/handle/10251/82834
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2014-59242-C2-1-R TECNICAS AVANZADAS DE PROCESADO PARA SISTEMAS ACTIVOS ENCAPSULADOS
Generalitat Valenciana https://doi.org/10.13039/501100003359 GV%2F2014%2F008
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reserva de todos los derechos
http://rightsstatements.org/vocab/InC/1.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.300719

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