Green synthesis of imine-based covalent organic frameworks in water

Dynamic covalent bonds have been advantageously used to direct the synthesis of crystalline porous covalent organic frameworks (COFs). Unlike the standard synthetic protocols that involve harsh conditions, this work provides a high-yield "one-pot"green synthesis of imine-based COFs in wate...

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Bibliographic Details
Authors: Martín-Illán, Jesús A., Rodríguez-San-Miguel, David|||0000-0002-1476-2175, Franco, Carlos|||0000-0003-3385-2851, Imaz, Inhar|||0000-0002-0278-1141, Maspoch Comamala, Daniel|||0000-0003-1325-9161, Puigmarti-Luis, Josep|||0000-0002-7510-9815, Zamora, Félix|||0000-0001-7529-5120
Format: article
Publication Date:2020
Country:España
Institution:Universitat Autònoma de Barcelona
Repository:Dipòsit Digital de Documents de la UAB
Language:English
OAI Identifier:oai:ddd.uab.cat:233950
Online Access:https://ddd.uab.cat/record/233950
https://dx.doi.org/urn:doi:10.1039/d0cc02033h
Access Level:Open access
Keyword:Aqueous synthesis
Covalent organic frameworks
High yield
Microwave conditions
One pot
Synthetic protocols
Description
Summary:Dynamic covalent bonds have been advantageously used to direct the synthesis of crystalline porous covalent organic frameworks (COFs). Unlike the standard synthetic protocols that involve harsh conditions, this work provides a high-yield "one-pot"green synthesis of imine-based COFs in water. Additionally, this aqueous synthesis can be performed under microwave conditions, considerably reducing the reaction time.

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