Green synthesis of imine-based covalent organic frameworks in water

Dynamic covalent bonds have been advantageously used to direct the synthesis of crystalline porous covalent organic frameworks (COFs). Unlike the standard synthetic protocols that involve harsh conditions, this work provides a high-yield "one-pot"green synthesis of imine-based COFs in wate...

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Detalles Bibliográficos
Autores: Martín-Illán, Jesús A., Rodríguez-San-Miguel, David|||0000-0002-1476-2175, Franco, Carlos|||0000-0003-3385-2851, Imaz, Inhar|||0000-0002-0278-1141, Maspoch Comamala, Daniel|||0000-0003-1325-9161, Puigmarti-Luis, Josep|||0000-0002-7510-9815, Zamora, Félix|||0000-0001-7529-5120
Tipo de recurso: artículo
Fecha de publicación:2020
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:233950
Acceso en línea:https://ddd.uab.cat/record/233950
https://dx.doi.org/urn:doi:10.1039/d0cc02033h
Access Level:acceso abierto
Palabra clave:Aqueous synthesis
Covalent organic frameworks
High yield
Microwave conditions
One pot
Synthetic protocols
Descripción
Sumario:Dynamic covalent bonds have been advantageously used to direct the synthesis of crystalline porous covalent organic frameworks (COFs). Unlike the standard synthetic protocols that involve harsh conditions, this work provides a high-yield "one-pot"green synthesis of imine-based COFs in water. Additionally, this aqueous synthesis can be performed under microwave conditions, considerably reducing the reaction time.