Direct access to parent amido complexes of rhodium and iridium through N-H activation of ammonia

Simplicity! A direct entry to amido rhodium and iridium complexes was easily achieved by reaction of gaseous ammonia with alkoxo-bridged precursors under very mild conditions. This new approach allowed the high-yield access for the first time to elusive [Rh-NH 2] complexes. Copyright © 2011 WILEY-V...

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Detalles Bibliográficos
Autores: Mena, Inmaculada, Casado, Miguel A., García-Orduña, Pilar, Polo, Víctor, Lahoz, Fernando J., Fazal, Atif, Oro, Luis A.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2011
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/64560
Acceso en línea:http://hdl.handle.net/10261/64560
Access Level:acceso abierto
Descripción
Sumario:Simplicity! A direct entry to amido rhodium and iridium complexes was easily achieved by reaction of gaseous ammonia with alkoxo-bridged precursors under very mild conditions. This new approach allowed the high-yield access for the first time to elusive [Rh-NH 2] complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.