Ligand-controlled Regiodivergent Ni-Catalyzed Reductive Carboxylation of Allyl Esters with CO2

<p> A novel Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO<sub>2</sub> has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.</p>

Detalhes bibliográficos
Autores: Moragas, Toni, Cornella, Josep, Martin,Ruben
Tipo de documento: artigo
Data de publicação:2014
País:España
Recursos:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositório:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2072/305832
Acesso em linha:http://hdl.handle.net/2072/305832
https://doi.org/10.1021/ja509077a
Access Level:Acceso aberto
Descrição
Resumo:<p> A novel Ni-catalyzed regiodivergent reductive carboxylation of allyl esters with CO<sub>2</sub> has been developed. This mild, user-friendly, and operationally simple method is characterized by an exquisite selectivity profile that is dictated by the ligand backbone.</p>