Photoredox-Assisted Gold-Catalyzed Arylative Alkoxycyclization of 1,6-Enynes
The photoredox-assisted gold-catalyzed arylative cyclization of 1,6-enynes with aryldiazonium salts gives rise to cyclization products with the opposite configuration at the alkene than that obtained by gold(I)-catalyzed alkoxycyclization. The reaction occurs under mild conditions and shows high fun...
| Authors: | , , |
|---|---|
| Format: | article |
| Status: | Versión aceptada para publicación |
| Publication Date: | 2020 |
| Country: | España |
| Institution: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repository: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2072/447789 |
| Online Access: | http://hdl.handle.net/2072/447789 https://doi.org/10.1021/acs.orglett.0c00799 |
| Access Level: | Open access |
| Keyword: | 54 |
| Summary: | The photoredox-assisted gold-catalyzed arylative cyclization of 1,6-enynes with aryldiazonium salts gives rise to cyclization products with the opposite configuration at the alkene than that obtained by gold(I)-catalyzed alkoxycyclization. The reaction occurs under mild conditions and shows high functional group tolerance. |
|---|