Pentafluorophenyl complexes of cobalt(III) with 1-(diacetylmonoximatoimino)-3-(diacetylmonoximeimino)-propane (dotnH)
The treatment of Br2Co(dotnH) with the C6F5MgBr Grignard reagent leads to the isolation of (C6F5)BrCo(dotnH). Substitution reactions of this substances make it possible to isolate neutral complexes ((C6F5)CoX(dotnH) (X = CN-, SCN- I-, NO2-)), mononuclear cationic complexes ([C6F5)Co(dotnH)L]Y (L = H...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1977 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4934 |
| Acceso en línea: | http://hdl.handle.net/10017/4934 https://dx.doi.org/10.1016/S0022-328X(00)84421-6 |
| Access Level: | acceso abierto |
| Palabra clave: | Cobalt(III) Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | The treatment of Br2Co(dotnH) with the C6F5MgBr Grignard reagent leads to the isolation of (C6F5)BrCo(dotnH). Substitution reactions of this substances make it possible to isolate neutral complexes ((C6F5)CoX(dotnH) (X = CN-, SCN- I-, NO2-)), mononuclear cationic complexes ([C6F5)Co(dotnH)L]Y (L = H2O, NH3, py; Y = ClO4-, BPh4-) and binuclear cationic complexes ({(C6F5)Co-(dotnH)]2X} +BPh4-(X = CN-,SCN-)). The new complexes were studied by IR, visible-UV and NMR spectroscopy. |
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