Cyanomethyl cyclopentadienyl complexes of cobalt
The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have been investigated. Chloroacetonitrile reacts with CpCo(CO)PPh3 to give the cationic complex [CpCo(CH2CN)(CNCH2Cl)PPh3]+, which has been isolated and characterized. Compounds of the type [CpCo(CH2CN)(bipy...
| Autores: | , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1978 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4818 |
| Acceso en línea: | http://hdl.handle.net/10017/4818 https://dx.doi.org/10.1016/S0022-328X(00)91925-9 |
| Access Level: | acceso abierto |
| Palabra clave: | Cyanomethyl cyclopentadienyl complexes of cobalt Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | The reactions of the complexes CpCo(CO)L (Cp = cyclopentadienyl, L = CO, PPh3) with ClCH2CN have been investigated. Chloroacetonitrile reacts with CpCo(CO)PPh3 to give the cationic complex [CpCo(CH2CN)(CNCH2Cl)PPh3]+, which has been isolated and characterized. Compounds of the type [CpCo(CH2CN)(bipy)]+ BPh4− and CpCo(CH2CN)PPh3CN have been obtained by substitution reactions. |
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