Reactions of complexes of gold(I) with bis(pentafluorophenyl)thallium(III) halides
The reactions of bis(pentafluorophenyl)thallium(III) halides with XAuL (L = PPh3, AsPh3) lead to results which vary according to the character of X. When X is Cl, Br or I an oxidation from gold(I) to gold(III) takes place through the transference of two C6F5 groups, and with the simultaneous precipi...
| Autores: | , , |
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| Tipo de recurso: | artículo |
| Fecha de publicación: | 1974 |
| País: | España |
| Institución: | Universidad de Alcalá (UAH) |
| Repositorio: | e_Buah Biblioteca Digital Universidad de Alcalá |
| Idioma: | inglés |
| OAI Identifier: | oai:ebuah.uah.es:10017/4939 |
| Acceso en línea: | http://hdl.handle.net/10017/4939 https://dx.doi.org/10.1016/S0022-328X(00)89739-9 |
| Access Level: | acceso abierto |
| Palabra clave: | Gold(I) Bis(pentafluorophenyl)thallium(III) halides Ciencia Química inorgánica Science Chemistry, inorganic |
| Sumario: | The reactions of bis(pentafluorophenyl)thallium(III) halides with XAuL (L = PPh3, AsPh3) lead to results which vary according to the character of X. When X is Cl, Br or I an oxidation from gold(I) to gold(III) takes place through the transference of two C6F5 groups, and with the simultaneous precipitation of thallous halide. When X is C6F5, C6H5, NO3, CH3COO, SCN or PPh3 substitution but not oxidation takes place, which may be followed by secondary reactions. Reasons for this behaviour are discussed. |
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