Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH

Hydrogel materials offer many advantages for chemical and biological sensoring due to their response to a small change in their environment with a related change in volume. Several designs have been outlined in the literature in the specific field of hydrogel-based optical sensors, reporting a large...

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Autores: Francone, Achille, Kehoe, Timothy, Obieta, Isabel, Sáez-Martínez, Virginia, Bilbao, Leire, Khokhar, Ali Z., Gadegaard, Nikolaj, Simao, Claudia, Kehagias, N., Sotomayor Torres, C. M.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2018
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/199564
Acceso en línea:http://hdl.handle.net/10261/199564
Access Level:acceso abierto
Palabra clave:Hydrogen
Waveguide
Thermal nanoimprint lithography
Water sensor
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spelling Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pHFrancone, AchilleKehoe, TimothyObieta, IsabelSáez-Martínez, VirginiaBilbao, LeireKhokhar, Ali Z.Gadegaard, NikolajSimao, ClaudiaKehagias, N.Sotomayor Torres, C. M.HydrogenWaveguideThermal nanoimprint lithographyWater sensorHydrogel materials offer many advantages for chemical and biological sensoring due to their response to a small change in their environment with a related change in volume. Several designs have been outlined in the literature in the specific field of hydrogel-based optical sensors, reporting a large number of steps for their fabrication. In this work we present a three-dimensional, hydrogel-based sensor the structure of which is fabricated in a single step using thermal nanoimprint lithography. The sensor is based on a waveguide with a grating readout section. A specific hydrogel formulation, based on a combination of PEGDMA (Poly(Ethylene Glycol DiMethAcrylate)), NIPAAm (N-IsoPropylAcrylAmide), and AA (Acrylic Acid), was developed. This stimulus-responsive hydrogel is sensitive to pH and to water. Moreover, the hydrogel has been modified to be suitable for fabrication by thermal nanoimprint lithography. Once stimulated, the hydrogel-based sensor changes its topography, which is characterised physically by AFM and SEM, and optically using a specific optical set-up.The authors acknowledge the financial support from: the EU project, NAPANIL project (No. FP7-CP-IP 214249), the MINECO project PHENTOM (No. FIS2015-70862). ICN2 acknowledges support from the Severo Ochoa Program (MINECO, Grant SEV-2013-0295) and funding from the CERCA Programme/Generalitat de Catalunya.Peer reviewedMultidisciplinary Digital Publishing InstituteEuropean CommissionMinisterio de Economía y Competitividad (España)Generalitat de CatalunyaFrancone, Achille [0000-0001-7757-9901]Kehoe, Timothy [0000-0002-7051-5910]Obieta, Isabel [0000-0002-9132-6609]Saez-Martinez, Virginia [0000-0003-4061-3410]Sotomayor Torres, C. M. [000-0001-9986-2716]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202020202018info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/199564reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/FP7/214249info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2013-0295info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/FIS2015-70862-Phttps://doi.org/10.3390/s18103240Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1995642026-05-22T06:33:51Z
dc.title.none.fl_str_mv Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
title Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
spellingShingle Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
Francone, Achille
Hydrogen
Waveguide
Thermal nanoimprint lithography
Water sensor
title_short Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
title_full Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
title_fullStr Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
title_full_unstemmed Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
title_sort Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
dc.creator.none.fl_str_mv Francone, Achille
Kehoe, Timothy
Obieta, Isabel
Sáez-Martínez, Virginia
Bilbao, Leire
Khokhar, Ali Z.
Gadegaard, Nikolaj
Simao, Claudia
Kehagias, N.
Sotomayor Torres, C. M.
author Francone, Achille
author_facet Francone, Achille
Kehoe, Timothy
Obieta, Isabel
Sáez-Martínez, Virginia
Bilbao, Leire
Khokhar, Ali Z.
Gadegaard, Nikolaj
Simao, Claudia
Kehagias, N.
Sotomayor Torres, C. M.
author_role author
author2 Kehoe, Timothy
Obieta, Isabel
Sáez-Martínez, Virginia
Bilbao, Leire
Khokhar, Ali Z.
Gadegaard, Nikolaj
Simao, Claudia
Kehagias, N.
Sotomayor Torres, C. M.
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv European Commission
Ministerio de Economía y Competitividad (España)
Generalitat de Catalunya
Francone, Achille [0000-0001-7757-9901]
Kehoe, Timothy [0000-0002-7051-5910]
Obieta, Isabel [0000-0002-9132-6609]
Saez-Martinez, Virginia [0000-0003-4061-3410]
Sotomayor Torres, C. M. [000-0001-9986-2716]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Hydrogen
Waveguide
Thermal nanoimprint lithography
Water sensor
topic Hydrogen
Waveguide
Thermal nanoimprint lithography
Water sensor
description Hydrogel materials offer many advantages for chemical and biological sensoring due to their response to a small change in their environment with a related change in volume. Several designs have been outlined in the literature in the specific field of hydrogel-based optical sensors, reporting a large number of steps for their fabrication. In this work we present a three-dimensional, hydrogel-based sensor the structure of which is fabricated in a single step using thermal nanoimprint lithography. The sensor is based on a waveguide with a grating readout section. A specific hydrogel formulation, based on a combination of PEGDMA (Poly(Ethylene Glycol DiMethAcrylate)), NIPAAm (N-IsoPropylAcrylAmide), and AA (Acrylic Acid), was developed. This stimulus-responsive hydrogel is sensitive to pH and to water. Moreover, the hydrogel has been modified to be suitable for fabrication by thermal nanoimprint lithography. Once stimulated, the hydrogel-based sensor changes its topography, which is characterised physically by AFM and SEM, and optically using a specific optical set-up.
publishDate 2018
dc.date.none.fl_str_mv 2018
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/199564
url http://hdl.handle.net/10261/199564
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/EC/FP7/214249
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2013-0295
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/FIS2015-70862-P
https://doi.org/10.3390/s18103240

dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
publisher.none.fl_str_mv Multidisciplinary Digital Publishing Institute
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
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repository.mail.fl_str_mv
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