Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH
Hydrogel materials offer many advantages for chemical and biological sensoring due to their response to a small change in their environment with a related change in volume. Several designs have been outlined in the literature in the specific field of hydrogel-based optical sensors, reporting a large...
| Autores: | , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2018 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/199564 |
| Acceso en línea: | http://hdl.handle.net/10261/199564 |
| Access Level: | acceso abierto |
| Palabra clave: | Hydrogen Waveguide Thermal nanoimprint lithography Water sensor |
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Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pHFrancone, AchilleKehoe, TimothyObieta, IsabelSáez-Martínez, VirginiaBilbao, LeireKhokhar, Ali Z.Gadegaard, NikolajSimao, ClaudiaKehagias, N.Sotomayor Torres, C. M.HydrogenWaveguideThermal nanoimprint lithographyWater sensorHydrogel materials offer many advantages for chemical and biological sensoring due to their response to a small change in their environment with a related change in volume. Several designs have been outlined in the literature in the specific field of hydrogel-based optical sensors, reporting a large number of steps for their fabrication. In this work we present a three-dimensional, hydrogel-based sensor the structure of which is fabricated in a single step using thermal nanoimprint lithography. The sensor is based on a waveguide with a grating readout section. A specific hydrogel formulation, based on a combination of PEGDMA (Poly(Ethylene Glycol DiMethAcrylate)), NIPAAm (N-IsoPropylAcrylAmide), and AA (Acrylic Acid), was developed. This stimulus-responsive hydrogel is sensitive to pH and to water. Moreover, the hydrogel has been modified to be suitable for fabrication by thermal nanoimprint lithography. Once stimulated, the hydrogel-based sensor changes its topography, which is characterised physically by AFM and SEM, and optically using a specific optical set-up.The authors acknowledge the financial support from: the EU project, NAPANIL project (No. FP7-CP-IP 214249), the MINECO project PHENTOM (No. FIS2015-70862). ICN2 acknowledges support from the Severo Ochoa Program (MINECO, Grant SEV-2013-0295) and funding from the CERCA Programme/Generalitat de Catalunya.Peer reviewedMultidisciplinary Digital Publishing InstituteEuropean CommissionMinisterio de Economía y Competitividad (España)Generalitat de CatalunyaFrancone, Achille [0000-0001-7757-9901]Kehoe, Timothy [0000-0002-7051-5910]Obieta, Isabel [0000-0002-9132-6609]Saez-Martinez, Virginia [0000-0003-4061-3410]Sotomayor Torres, C. M. [000-0001-9986-2716]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202020202018info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/199564reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/EC/FP7/214249info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2013-0295info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/FIS2015-70862-Phttps://doi.org/10.3390/s18103240Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1995642026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH |
| title |
Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH |
| spellingShingle |
Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH Francone, Achille Hydrogen Waveguide Thermal nanoimprint lithography Water sensor |
| title_short |
Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH |
| title_full |
Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH |
| title_fullStr |
Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH |
| title_full_unstemmed |
Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH |
| title_sort |
Integrated 3D hydrogel waveguide out-coupler by step-and-repeat thermal nanoimprint lithography: A promising sensor device for water and pH |
| dc.creator.none.fl_str_mv |
Francone, Achille Kehoe, Timothy Obieta, Isabel Sáez-Martínez, Virginia Bilbao, Leire Khokhar, Ali Z. Gadegaard, Nikolaj Simao, Claudia Kehagias, N. Sotomayor Torres, C. M. |
| author |
Francone, Achille |
| author_facet |
Francone, Achille Kehoe, Timothy Obieta, Isabel Sáez-Martínez, Virginia Bilbao, Leire Khokhar, Ali Z. Gadegaard, Nikolaj Simao, Claudia Kehagias, N. Sotomayor Torres, C. M. |
| author_role |
author |
| author2 |
Kehoe, Timothy Obieta, Isabel Sáez-Martínez, Virginia Bilbao, Leire Khokhar, Ali Z. Gadegaard, Nikolaj Simao, Claudia Kehagias, N. Sotomayor Torres, C. M. |
| author2_role |
author author author author author author author author author |
| dc.contributor.none.fl_str_mv |
European Commission Ministerio de Economía y Competitividad (España) Generalitat de Catalunya Francone, Achille [0000-0001-7757-9901] Kehoe, Timothy [0000-0002-7051-5910] Obieta, Isabel [0000-0002-9132-6609] Saez-Martinez, Virginia [0000-0003-4061-3410] Sotomayor Torres, C. M. [000-0001-9986-2716] Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Hydrogen Waveguide Thermal nanoimprint lithography Water sensor |
| topic |
Hydrogen Waveguide Thermal nanoimprint lithography Water sensor |
| description |
Hydrogel materials offer many advantages for chemical and biological sensoring due to their response to a small change in their environment with a related change in volume. Several designs have been outlined in the literature in the specific field of hydrogel-based optical sensors, reporting a large number of steps for their fabrication. In this work we present a three-dimensional, hydrogel-based sensor the structure of which is fabricated in a single step using thermal nanoimprint lithography. The sensor is based on a waveguide with a grating readout section. A specific hydrogel formulation, based on a combination of PEGDMA (Poly(Ethylene Glycol DiMethAcrylate)), NIPAAm (N-IsoPropylAcrylAmide), and AA (Acrylic Acid), was developed. This stimulus-responsive hydrogel is sensitive to pH and to water. Moreover, the hydrogel has been modified to be suitable for fabrication by thermal nanoimprint lithography. Once stimulated, the hydrogel-based sensor changes its topography, which is characterised physically by AFM and SEM, and optically using a specific optical set-up. |
| publishDate |
2018 |
| dc.date.none.fl_str_mv |
2018 2020 2020 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion |
| format |
article |
| status_str |
publishedVersion |
| dc.identifier.none.fl_str_mv |
http://hdl.handle.net/10261/199564 |
| url |
http://hdl.handle.net/10261/199564 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
#PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# #PLACEHOLDER_PARENT_METADATA_VALUE# info:eu-repo/grantAgreement/EC/FP7/214249 info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SEV-2013-0295 info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/FIS2015-70862-P https://doi.org/10.3390/s18103240 Sí |
| dc.rights.none.fl_str_mv |
info:eu-repo/semantics/openAccess |
| eu_rights_str_mv |
openAccess |
| dc.publisher.none.fl_str_mv |
Multidisciplinary Digital Publishing Institute |
| publisher.none.fl_str_mv |
Multidisciplinary Digital Publishing Institute |
| dc.source.none.fl_str_mv |
reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
| instname_str |
Consejo Superior de Investigaciones Científicas (CSIC) |
| reponame_str |
DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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| repository.mail.fl_str_mv |
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1869411405696860161 |
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15,198674 |