NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids

[EN] Upconversion nanohybrids (UCNHs) consisting of rose bengal (RB) and upconversion nanoparticles (UCNPs) are able to promote terpinene oxidation upon near-infrared irradiation. The photophysical events occurring upon NIR-irradiation of the UCNH correlate well with the synthetic protocol used to p...

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Autores: Francés-Soriano, Laura|||0000-0002-5630-4199, Bellezza, Delia, Ferrera-Gónzalez, Juan, Gonzalez-Béjar, María, Perez-Prieto, Julia
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/229547
Acceso en línea:https://riunet.upv.es/handle/10251/229547
Access Level:acceso abierto
Palabra clave:Upconversion nanohybrids
Rose bengal
Upconversion nanoparticles
Near-infrared irradiation
Photocatalysis
Material optimization
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spelling NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybridsFrancés-Soriano, Laura|||0000-0002-5630-4199Bellezza, DeliaFerrera-Gónzalez, JuanGonzalez-Béjar, MaríaPerez-Prieto, JuliaUpconversion nanohybridsRose bengalUpconversion nanoparticlesNear-infrared irradiationPhotocatalysisMaterial optimization[EN] Upconversion nanohybrids (UCNHs) consisting of rose bengal (RB) and upconversion nanoparticles (UCNPs) are able to promote terpinene oxidation upon near-infrared irradiation. The photophysical events occurring upon NIR-irradiation of the UCNH correlate well with the synthetic protocol used to prepare the UCNHs (RB loading and aggregation). These results highlight the importance of the optimization of UCNH composition for the photocatalysis outcome.This research was funded by Agencia Estatal de InvestigacionAEI (grant number MMCIU Unit of Excellence Maria de Maeztu CEX2019-000919-M); Ministerio de Universidades (Maria Zambrano contract L. F. S. (ZA21-037)); and Generalitat Valenciana (IDIFEDER/2018/064 and IDIFEDER/2021/064), all of them partially cofinanced with FEDER funds. This study forms part of the Advanced Materials programme (MFA/2022/ 051) and was supported by MICIN with funding from European Union NextGenerationEU (PRTR-C17.I1) and by Generalitat Valenciana. We also thank Universitat de Valencia (Programa Propi del Vicerectorat d'Investigacio de la UV (UV-INV_AE2653809).Royal Society of ChemistryDepartamento de Ingeniería Textil y PapeleraGrupo de Procesos de Oxidación AvanzadaEuropean CommissionGeneralitat ValencianaUniversitat de ValènciaEuropean Regional Development FundMinisterio de Ciencia e InnovaciónRepositorio Institucional de la Universitat Politècnica de València Riunet20242024-11-19journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/229547reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengGeneralitat Valenciana https://doi.org/10.13039/501100003359 IDIFEDER%2F2018%2F064Generalitat Valenciana https://doi.org/10.13039/501100003359 IDIFEDER%2F2021%2F064Universitat de València https://doi.org/10.13039/100008457 UV-INV_AE2653809Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 MFA%2F2022%2F051Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 CEX2019-000919-Mopen accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial (by-nc) http://creativecommons.org/licenses/by-nc/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/2295472026-06-13T07:49:27Z
dc.title.none.fl_str_mv NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids
title NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids
spellingShingle NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids
Francés-Soriano, Laura|||0000-0002-5630-4199
Upconversion nanohybrids
Rose bengal
Upconversion nanoparticles
Near-infrared irradiation
Photocatalysis
Material optimization
title_short NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids
title_full NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids
title_fullStr NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids
title_full_unstemmed NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids
title_sort NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids
dc.creator.none.fl_str_mv Francés-Soriano, Laura|||0000-0002-5630-4199
Bellezza, Delia
Ferrera-Gónzalez, Juan
Gonzalez-Béjar, María
Perez-Prieto, Julia
author Francés-Soriano, Laura|||0000-0002-5630-4199
author_facet Francés-Soriano, Laura|||0000-0002-5630-4199
Bellezza, Delia
Ferrera-Gónzalez, Juan
Gonzalez-Béjar, María
Perez-Prieto, Julia
author_role author
author2 Bellezza, Delia
Ferrera-Gónzalez, Juan
Gonzalez-Béjar, María
Perez-Prieto, Julia
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Textil y Papelera
Grupo de Procesos de Oxidación Avanzada
European Commission
Generalitat Valenciana
Universitat de València
European Regional Development Fund
Ministerio de Ciencia e Innovación
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Upconversion nanohybrids
Rose bengal
Upconversion nanoparticles
Near-infrared irradiation
Photocatalysis
Material optimization
topic Upconversion nanohybrids
Rose bengal
Upconversion nanoparticles
Near-infrared irradiation
Photocatalysis
Material optimization
description [EN] Upconversion nanohybrids (UCNHs) consisting of rose bengal (RB) and upconversion nanoparticles (UCNPs) are able to promote terpinene oxidation upon near-infrared irradiation. The photophysical events occurring upon NIR-irradiation of the UCNH correlate well with the synthetic protocol used to prepare the UCNHs (RB loading and aggregation). These results highlight the importance of the optimization of UCNH composition for the photocatalysis outcome.
publishDate 2024
dc.date.none.fl_str_mv 2024
2024-11-19
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/229547
url https://riunet.upv.es/handle/10251/229547
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Generalitat Valenciana https://doi.org/10.13039/501100003359 IDIFEDER%2F2018%2F064
Generalitat Valenciana https://doi.org/10.13039/501100003359 IDIFEDER%2F2021%2F064
Universitat de València https://doi.org/10.13039/100008457 UV-INV_AE2653809
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 MFA%2F2022%2F051
Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 CEX2019-000919-M
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial (by-nc)
http://creativecommons.org/licenses/by-nc/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento - No comercial (by-nc)
http://creativecommons.org/licenses/by-nc/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
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