NIR-triggered photooxygenation of alfa-terpinene with upconversion nanohybrids

[EN] Upconversion nanohybrids (UCNHs) consisting of rose bengal (RB) and upconversion nanoparticles (UCNPs) are able to promote terpinene oxidation upon near-infrared irradiation. The photophysical events occurring upon NIR-irradiation of the UCNH correlate well with the synthetic protocol used to p...

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Detalles Bibliográficos
Autores: Francés-Soriano, Laura|||0000-0002-5630-4199, Bellezza, Delia, Ferrera-Gónzalez, Juan, Gonzalez-Béjar, María, Perez-Prieto, Julia
Tipo de recurso: artículo
Fecha de publicación:2024
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/229547
Acceso en línea:https://riunet.upv.es/handle/10251/229547
Access Level:acceso abierto
Palabra clave:Upconversion nanohybrids
Rose bengal
Upconversion nanoparticles
Near-infrared irradiation
Photocatalysis
Material optimization
Descripción
Sumario:[EN] Upconversion nanohybrids (UCNHs) consisting of rose bengal (RB) and upconversion nanoparticles (UCNPs) are able to promote terpinene oxidation upon near-infrared irradiation. The photophysical events occurring upon NIR-irradiation of the UCNH correlate well with the synthetic protocol used to prepare the UCNHs (RB loading and aggregation). These results highlight the importance of the optimization of UCNH composition for the photocatalysis outcome.