Palladium-Catalyzed Transformations of Alkylidenecyclopropanes

Organic synthesis has profoundly impacted fields such as medicinal chemistry, materials science, and agriculture by enabling the creation of complex molecular structures beyond those found in nature. In recent years, the field has embraced sustainable practices aligned with green chemistry principle...

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Bibliographic Details
Author: Rodiño Balboa, Ricardo
Format: doctoral thesis
Publication Date:2025
Country:España
Institution:Universidad de Santiago de Compostela (USC)
Repository:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Language:English
OAI Identifier:oai:minerva.usc.gal:10347/41048
Online Access:https://hdl.handle.net/10347/41048
Access Level:Open access
Keyword:alkylidenecyclopropane
palladium
transition-metal catalysis
heterocycles
cross-coupling
230610 Compuestos heterocíclicos
230611 Compuestos organometálicos
230615 Mecanismos de reacción
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repository_id_str
spelling Palladium-Catalyzed Transformations of AlkylidenecyclopropanesRodiño Balboa, Ricardoalkylidenecyclopropanepalladiumtransition-metal catalysisheterocyclescross-coupling230610 Compuestos heterocíclicos230611 Compuestos organometálicos230615 Mecanismos de reacciónOrganic synthesis has profoundly impacted fields such as medicinal chemistry, materials science, and agriculture by enabling the creation of complex molecular structures beyond those found in nature. In recent years, the field has embraced sustainable practices aligned with green chemistry principles, prioritizing efficiency, environmental responsibility, and atom economy. In this context, catalysis has emerged as a key synthetic tool, driving more selective and efficient reactions, often under milder conditions, and thereby reducing waste and energy consumption. Among homogeneous catalytic methods, where catalysts and reactants are in the same phase, organometallic complexes featuring transition metals stand out for their tunable electronic and steric properties, which have afforded to broaden significantly the range of achievable chemical transformations, making previously challenging reactions feasible.López García, Fernando JoséMascareñas Cid, José LuisUniversidade de Santiago de Compostela. Escola de Doutoramento Internacional (EDIUS)20252025-01-0120252025-01-01doctoral thesishttp://purl.org/coar/resource_type/c_db06info:eu-repo/semantics/doctoralThesisapplication/pdfhttps://hdl.handle.net/10347/41048reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostelainstname:Universidad de Santiago de Compostela (USC)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:minerva.usc.gal:10347/410482026-06-15T12:47:27Z
dc.title.none.fl_str_mv Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
title Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
spellingShingle Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
Rodiño Balboa, Ricardo
alkylidenecyclopropane
palladium
transition-metal catalysis
heterocycles
cross-coupling
230610 Compuestos heterocíclicos
230611 Compuestos organometálicos
230615 Mecanismos de reacción
title_short Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
title_full Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
title_fullStr Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
title_full_unstemmed Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
title_sort Palladium-Catalyzed Transformations of Alkylidenecyclopropanes
dc.creator.none.fl_str_mv Rodiño Balboa, Ricardo
author Rodiño Balboa, Ricardo
author_facet Rodiño Balboa, Ricardo
author_role author
dc.contributor.none.fl_str_mv López García, Fernando José
Mascareñas Cid, José Luis
Universidade de Santiago de Compostela. Escola de Doutoramento Internacional (EDIUS)
dc.subject.none.fl_str_mv alkylidenecyclopropane
palladium
transition-metal catalysis
heterocycles
cross-coupling
230610 Compuestos heterocíclicos
230611 Compuestos organometálicos
230615 Mecanismos de reacción
topic alkylidenecyclopropane
palladium
transition-metal catalysis
heterocycles
cross-coupling
230610 Compuestos heterocíclicos
230611 Compuestos organometálicos
230615 Mecanismos de reacción
description Organic synthesis has profoundly impacted fields such as medicinal chemistry, materials science, and agriculture by enabling the creation of complex molecular structures beyond those found in nature. In recent years, the field has embraced sustainable practices aligned with green chemistry principles, prioritizing efficiency, environmental responsibility, and atom economy. In this context, catalysis has emerged as a key synthetic tool, driving more selective and efficient reactions, often under milder conditions, and thereby reducing waste and energy consumption. Among homogeneous catalytic methods, where catalysts and reactants are in the same phase, organometallic complexes featuring transition metals stand out for their tunable electronic and steric properties, which have afforded to broaden significantly the range of achievable chemical transformations, making previously challenging reactions feasible.
publishDate 2025
dc.date.none.fl_str_mv 2025
2025-01-01
2025
2025-01-01
dc.type.none.fl_str_mv doctoral thesis
http://purl.org/coar/resource_type/c_db06
dc.type.openaire.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
dc.identifier.none.fl_str_mv https://hdl.handle.net/10347/41048
url https://hdl.handle.net/10347/41048
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
instname:Universidad de Santiago de Compostela (USC)
instname_str Universidad de Santiago de Compostela (USC)
reponame_str Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
collection Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.198674

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